| Identification | Back Directory | [Name]
CARYOPHYLLENE OXIDE | [CAS]
1139-30-6 | [Synonyms]
0s)-
,6r,10s)-
6r*,10s*))-r
caryophyleneoxide
CARYOPHYLLENEPOXID
Caryophylene oxide
Caryophyllene oxyde
CARYOPHYLLENE OXIDE
caryophylleneepoxide
CARYLOPHYLLENE OXIDE
Caryophyllene epoxide
(-)-EPOXYCARYOPHYLLENE
(-)-CARYOPHYLLENE OXIDE
beta-caryophylleneoxide
beta-Caryophyllene oxide
4theta,6theta,10s)]-thet
beta-caryophylleneepoxide
CARYOPHYLLENE OXIDE 95+%
(-)-CARYOPHYLLENE OXIDE 95%
(-)-Caryophyllene oxide,97%
(-)-beta-caryophylleneepoxid
(-)-beta-caryophylleneepoxide
(-)-Epoxydihydrocaryophyllene
(-)-beta-Caryophyllene epoxide
CARYOPHYLLENE OXIDE TECH. 90%
(-)-Caryophyllene oxide, 95% 10GR
(-)-CARYOPHYLLENE OXIDE, >= 99.0 % G
(1r-(1r,4r,6r,10s))-4,12,12-trimethyl
4,11,11-Trimethyl-8-methylene-5-oxatricyclo(8.2.0.0(4,6))dodecane
5-oxatricyclo[8.2.0.04,6]dodecane,,12,12-trimethyl-3-methylene-[1r-
6]dodecane,4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.0[1theta-(1
(1β,4R,5R,9α)-4,11,11-Trimethyl-8-methylene-4,5-epoxybicyclo[7.2.0]undecane
5-oxatricyclo(8.2.0.0(sup4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r,4r
5-oxatricyclo(8.2.0.0(4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r-(1r*,4
5-oxatricyclo(8.20.0(4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r,4r,6r,1
(1R,4R,6R,10S)-4,12,12-Trimethyl-9-methylene-5-oxatricyclo[8.2.0.04,6]dodecane
(1R,5S,8R,11R)-4-Methylene-7,7,11-trimethyl-12-oxatricyclo[9.1.0.05,8]dodecane
5-Oxatricyclo8.2.0.04,6dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)-
(1R,4R,6R,10S)-9-METHYLENE-4,12,12-TRIMETHYL-5-OXATRICYCLO[8.2.0.0(4,6)]DODECANE
4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.]dodecane (caryophyllene oxide)
(1r-(1r,4r,6r,10s))-4,12,12-trimethyl-9-methylene-5-oxatricyclo(8.2.0.04,6)dodecane
(1R-(1R*,4R*,6R*,10S*))-4,12,12-Trimethyl-9-methylen-5-oxatricyclo(8.2.0.04,6)dodecan
(1r-(1r*,4r*,6r*,10s*))-4,12,12-trimethyl-9-methylene-5-oxatricyclo(8.2.0.04,6)dodecane
6]dodecane,4,12,12-trimethyl-9-methylene-,[1R-(1R*,4R*,6R*,10S*)]-5-Oxatricyclo[8.2.0.04
5-)xatricyclo[8.2.0.0(4,6))dodecane, 6,,11,11-trimethyl-2-methylene, [1R-(1R*,4R*,6R*,10S*)]-
5-Oxatricyclo(8.2.0.04,6)dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)-
5-Oxatricyclo[8.2.0.0(4,6)-]dodecane, 4,12,12-trimethyl-9-methylene-, [1R-(1R*,4R*,6R*,10S*)]-
(-)-5-Oxatricyclo[8.2.0.0(4,6)]dodecane,4,12,12-trimethyl-9-methylene-, [1R-(1R*,4R*,6R*,10S*)]-
caryophylleneoxide,(1R,4R,6R,10S)-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.0]4,6)]dodecane
(-)-Epoxycaryophyllene, (1R,4R,6R,10S)-9-Methylene-4,12,12-trimethyl-5-oxatricyclo[8.2.0.04,6]dodecane | [EINECS(EC#)]
214-519-7 | [Molecular Formula]
C15H24O | [MDL Number]
MFCD00134216 | [MOL File]
1139-30-6.mol | [Molecular Weight]
220.35 |
| Chemical Properties | Back Directory | [Appearance]
white crystalline powder | [Melting point ]
62-63 °C(lit.)
| [Boiling point ]
301.3°C (rough estimate) | [density ]
0.96
| [FEMA ]
4085 | BETA-CARYOPHYLLENE OXIDE | [refractive index ]
1.4956
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder | [color ]
White | [Odor]
at 100.00 %. sweet fresh dry woody spicy | [Odor Type]
woody | [optical activity]
[α]20/D 71±1°, c = 2% in chloroform | [Water Solubility ]
insoluble in water | [JECFA Number]
1575 | [BRN ]
148213 | [LogP]
4.57 | [EPA Substance Registry System]
5-Oxatricyclo[8.2.0.04,6]dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)- (1139-30-6) |
| Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder | [Definition]
ChEBI: A natural product found in Cupania cinerea. | [Occurrence]
Reported found in Nepeta betonicifolia C.A. Meyer oil Turkey (39.20%), geranium rose-scented oil (Pelargonium
spp.) Cuba (14.70%), melissa oil (9.99%), guava leaf oil Cuba (8.20%), etc. | [Uses]
β-Caryophyllene Epoxide, and its derivatives has shown to have microbial transformation and butyrylcholinesterase inhibitory activity. It is also the main active constituent of essential oils obtained from various plants, used for flavoring and fragrances. | [Aroma threshold values]
Medium strength odor, woody type. | [storage]
Store at -20°C | [Purification Methods]
Purify the oxide by TLC on silica gel with EtOAc/pet ether (b 60-80o) (15:85), and recrystallise it from MeOH or *C6H6. [NMR: Warnhoff Can J Chem 42 1664 1964, Ramage & Whitehead J Chem Soc 4336 1954, Beilstein 17 IV 392.] |
|
|