ChemicalBook--->CAS DataBase List--->1192-37-6

1192-37-6

1192-37-6 Structure

1192-37-6 Structure
IdentificationBack Directory
[Name]

METHYLENECYCLOHEXANE
[CAS]

1192-37-6
[Synonyms]

methylene-cyclohexan
METHYLENECYCLOHEXANE
Methycenecyclohexane
1-Methylenecyclohexane
cyclohexane,methylene-
Methylenecyclohexane,98%
Methylenecyclohexane,99+%
Methylenecyclohexane, 98% 1GR
[EINECS(EC#)]

214-752-4
[Molecular Formula]

C7H12
[MDL Number]

MFCD00001661
[MOL File]

1192-37-6.mol
[Molecular Weight]

96.17
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

-106.7°C
[Boiling point ]

102-103 °C(lit.)
[density ]

0.8 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.449(lit.)
[Fp ]

20 °F
[storage temp. ]

0-6°C
[form ]

Liquid
[color ]

Clear colorless
[Stability:]

Stable. Highly flammable. Incompatible with strong oxidizing agents. Refrigerate.
[BRN ]

773760
[EPA Substance Registry System]

Cyclohexane, methylene- (1192-37-6)
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
[Uses]

Methylenecyclohexane is excellent building block for organic molecules.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 100, p. 3611, 1978 DOI: 10.1021/ja00479a061
The Journal of Organic Chemistry, 48, p. 326, 1983 DOI: 10.1021/jo00151a010
Tetrahedron Letters, 25, p. 4901, 1984 DOI: 10.1016/S0040-4039(01)91254-7
[General Description]

Methylenecyclohexane ring is obtained by 1,4-addition of 4-pentenylmagnesium bromide to 2-cyano-2-cycloalkenones followed by a Pd(II)-mediated oxidative cyclization. It undergoes gas phase ozonolysis to form secondary organic aerosol (SOA).
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-65
[Safety Statements ]

16-23-24/25-62
[RIDADR ]

UN 3295 3/PG 2
[WGK Germany ]

3
[HazardClass ]

3.1
[PackingGroup ]

II
[HS Code ]

29021900
Spectrum DetailBack Directory
[Spectrum Detail]

METHYLENECYCLOHEXANE(1192-37-6)MS
METHYLENECYCLOHEXANE(1192-37-6)1HNMR
METHYLENECYCLOHEXANE(1192-37-6)13CNMR
METHYLENECYCLOHEXANE(1192-37-6)IR1
METHYLENECYCLOHEXANE(1192-37-6)Raman
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