ChemicalBook--->CAS DataBase List--->1375325-68-0

1375325-68-0

1375325-68-0 Structure

1375325-68-0 Structure
IdentificationBack Directory
[Name]

RuPhos Pd G2
[CAS]

1375325-68-0
[Synonyms]

RuPhos Pd G2
2nd Generation RuPhos Precatalyst
[2-(2-Aminophenyl)phenyl]-chloro-palladium
dicyclohexyl-[2-(2,6-diisopropoxyphenyl)phenyl]phosphane
Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II)
Chloro(2-dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
[2'-(Amino)[1,1'-biphenyl]-2-yl][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine]chloropalladium
(2'-Amino-[1,1'-biphenyl]-2-yl)(dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphoranyl)palladium(III) chloride
Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle]
[Molecular Formula]

C42H53ClNO2PPd
[MDL Number]

MFCD20264899
[MOL File]

1375325-68-0.mol
[Molecular Weight]

776.73
Chemical PropertiesBack Directory
[Melting point ]

195-197°C
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[form ]

Powder
[color ]

white
[InChIKey]

HAGBKELACJTOCE-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC(C)C)OC(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
[CAS DataBase Reference]

1375325-68-0
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H332-H335
[Precautionary statements ]

P261-P280-P305+P351+P338
[WGK Germany ]

3
Questions and Answers (Q&A)Back Directory
[Reactions]

Palladium precatalyst for fast Suzuki-Miyaura coupling reactions.
Reactions of 1375325-68-0
Hazard InformationBack Directory
[Uses]

RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.
[General Description]

RuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.
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