ChemicalBook--->CAS DataBase List--->2622-05-1

2622-05-1

2622-05-1 Structure

2622-05-1 Structure
IdentificationBack Directory
[Name]

Allylmagnesium chloride
[CAS]

2622-05-1
[Synonyms]

Allylchloromagnesium
Chloroallylmagnesium
Allylmagnesiumchlorid
ALLYLMAGNESIUM CHLORIDE
Allyl chlorideMagnesiuM
chloro-2-propenyl-magnesiu
2-Propenylmagnesium chloride
Magnesium, chloro-2-propenyl-
Allylmagnesium chloride solution
solutionpurum,2mintetrahydrofuran
AllylMagnesiuM Chloride, 1M in THF
Allylmagnesium chloride, 1M in MeTHF
Allylmagnesium chloride, 1.0 M in THF
ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I
Allylmagnesium chloride, 1.0 M in 2-MeTHF
Allylmagnesium chloride 2M solution in THF
Allylmagnesium chloride 1M solution in DEE
Allylmagnesium chloride 1.5M solution in THF
Allylmagnesium chloride, 1.7M solution in THF
ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF
Allylmagnesium Chloride 1.0 M In Tetrahydrofuran
Allylmagnesium Chloride 1.5 M in Tetrahydrofuran
Allylmagnesium chloride1.7M solution in THFAcroSeal§3
AllylMagnesiuM chloride, 1.7 M solution in THF, J&KSeal
Allylmagnesium chloride, 1.7M solution in THF, AcroSeal
AllylMagnesiuM chloride, 2.0 M solution in THF, SpcSeal
ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN
Allylmagnesium Chloride (10% in Tetrahydrofuran, ca. 1mol/L)
AllylMagnesiuM chloride, 1.7M solution in THF, AcroSeal 800ML
AllylMagnesiuM Chloride (ca. 9% in Tetrahydrofuran, ca. 0.9Mol/L)
Allylmagnesium Chloride (ca. 9% in Tetrahydrofuran, ca. 0.8mol/L)
Allylmagnesium Chloride (ca. 11% in Tetrahydrofuran, ca. 1.0mol/L)
[EINECS(EC#)]

220-067-1
[Molecular Formula]

C3H5ClMg
[MDL Number]

MFCD00000473
[MOL File]

2622-05-1.mol
[Molecular Weight]

100.83
Chemical PropertiesBack Directory
[Appearance]

clear tan to brown, amber, dark grey, dark green
[Melting point ]

-21°C
[Boiling point ]

66°C
[density ]

0.995 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

water-free area
[form ]

Liquid
[color ]

Clear tan to brown, amber, dark gray, dark green or black
[Water Solubility ]

vigorous reaction
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

3587316
[InChIKey]

PLYLAFITHJUEGX-UHFFFAOYSA-M
[EPA Substance Registry System]

Magnesium, chloro-2-propenyl-(2622-05-1)
Hazard InformationBack Directory
[Chemical Properties]

clear tan to brown, amber, dark grey, dark green
[Uses]

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Grignard-reactions: reagent for the introduction of the allyl group.
[Application]

Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.
[Precautions]

It reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions.
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

11-14/15-34-40-37-19
[Safety Statements ]

16-26-36/37/39-43-45-7/8-6A-43B-33
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

1
[F ]

1-3-10
[TSCA ]

Yes
[HazardClass ]

4.2
[PackingGroup ]

I
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Magnesium-->Allyl chloride
[Preparation Products]

3-METHYL-1,5-HEXADIENE-->1,6-HEPTADIEN-4-OL-->Tetraallyltin-->6-Chlorohex-1-ene-->ALLYL(DIISOPROPYL)(4-METHOXYPHENYL)SILANE-->Diallylzinc-->3-ALLYLOXETAN-3-OL
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