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28182-81-2

28182-81-2 Structure

28182-81-2 Structure
IdentificationBack Directory
[Name]

POLY(HEXAMETHYLENE DIISOCYANATE)
[CAS]

28182-81-2
[Synonyms]

THDI
coronateeh
DESMODURN3200
DESMODURN3300
homopolymerofhdi
hdi-basedisocyanurates
hexamethyleneisocyanatepolymer
hexamethylenediisocyanatetrimer
hexamethylenediisocyanatepolymer
POLY(HEXAMETHYLENE DIISOCYANATE)
1,6-diisocyanatohexanehomopolymer
1,6-diisocyanato-hexanhomopolymer
HEXANETHYLENEDIISOCYANATE POLYMER
Hexane,1,6-diisocyanato-,homopolymer
Hexamethylenediisocyanate,homopolymer
1,6-HEXAMETHYLENEDIISOCYANATEHOMOPOLYMER
isocyanicacid,hexamethyleneester,polymers
hexamethylenediisocyanatebasedisocyanurates
poly(hexamethylenediisocyanate)(desmodurn-100
1,6-DIISOCYANATEHEXAMETHYLENEISOCYANURATEHOMOPOLYMER
1,6-Hexamethylene Diisocyanate Based Polyisocyanate (HDI trimer)
POLY(HEXAMETHYLENE DIISOCYANATE) (DESMOD UR N-100 POLYISOCYANATE)
POLY(HEXAMETHYLENE DIISOCYANATE) (DESMOD UR N-3300 POLYISOCYANATE)
POLY(HEXAMETHYLENE DIISOCYANATE) (DESMOD UR N-3200 POLYISOCYANATE)
Poly(hexaMethylene diisocyanate) viscosity 1,300-2,200 cP (25 C)(lit.)
[EINECS(EC#)]

931-274-8
[Molecular Formula]

C8H12N2O2
[MDL Number]

MFCD00197906
[MOL File]

28182-81-2.mol
[Molecular Weight]

168.2
Chemical PropertiesBack Directory
[Appearance]

Hexamethylene diisocyanate is a colorless liquid. Sharp, irritating odor.
[density ]

1.169 g/mL at 25 °C
[vapor pressure ]

0.002-0.003Pa at 20-25℃
[refractive index ]

n20/D 1.506
[Fp ]

>230 °F
[LogP]

5.54-9.81
[EPA Substance Registry System]

Hexamethylene diisocyanate homopolymer (28182-81-2)
Hazard InformationBack Directory
[Chemical Properties]

Hexamethylene diisocyanate is a colorless liquid. Sharp, irritating odor.
[Potential Exposure]

Used to make other chemicals, coat ings, and polyurethane. It is also used as a hardener in automobile and airplane paints.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2281 Hexamethylene diisocyanate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

May form explosive mixture with air. Isocyanates are highly flammable and reactive with many compounds, even with themselves. Incompatible with oxi dizers (chlorates, nitrates, peroxides, permanganates, per chlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Reaction with moist air, water or alcohols may form amines and insoluble polyureas and react exothermically, releasing toxic, corrosive or flamma ble gases, including carbon dioxide; and, at the same time, may generate a violent release of heat increasing the con centration of fumes in the air. Incompatible with amines, aldehydes, alkali metals, ammonia, carboxylic acids, capro lactum, alkaline materials, glycols, ketones, mercaptans, hydrides, organotin catalysts, phenols, strong acids, strong bases, strong reducing agents such as hydrides, urethanes, ureas. Elevated temperatures or contact with acids, bases, tertiary amines, and acyl-chlorides may cause explosive polymerization. Attacks some plastics, rubber and coatings. Contact with metals may evolve flammable hydrogen gas. May accumulate static electrical charges, and may cause ignition of its vapors. Temperatures above 200℃ can cause polymerization. Attacks copper.
[Uses]

PolyHDI can be used as a compatibilizer to increase the complex viscosity of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/poly(lactic acid) biopolymer based blends. It can be used as a hardener that can be mixed with polyol resins to form polyurethane coatings with a wide range of applications like self-cleaning.
[General Description]

Poly(hexamethylene diisocyanate) (PolyHDI) is an aliphatic compound belonging to the class of isocyanates. It is generally prepared by reacting hexamethylene diamine with phosgene.
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

43-42/43-20-36
[Safety Statements ]

36/37-45-23-37-24-26
[RIDADR ]

UN 2810 6.1 / PGIII
[WGK Germany ]

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