| Identification | Back Directory | [Name]
4-*difluoro(3,4,5-trifluorophenoxy)-methyl]-3,5-difluoro-4'-propyl-1,1'-biphenyl | [CAS]
303186-20-1 | [Synonyms]
3PUQUF
PGQU 3F
PUQU 3F
3-BB(F,F)XB(F,F)-F
(3,5-difluoro-4'-propylbiphenyl-4-yl)(difluoro)methyl
(3,5-difluoro-4'-propylbiphenyl-4-yl)(difluoro)methyl 3,4,5-...
P-propyl-2,6-difluorobiphenyl-difluoromethoxy-3,4,5-trifluorobenzene
4-[Difluoro(3,4,5-trifluorophenoxy)methyl]-3,5-difluoro-4'-propylbiphenyl
3,5-Difluoro-4'-propyl-4-((3,4,5-trifluorophenoxy)difluoromethyl)biphenyl
3,5-difluoro-4-[(3,4,5-trifluorophenyl) difluoromethoxy ]-4'-propyl biphenyl
4-[Difluoro(3,4,5-trifluorophenoxy)methyl]-3,5-difluoro-4'-n-propylbiphenyl,99%
4-[Difluoro(3,4,5-trifluorophenoxy)methyl]-4′-propyl-3,5-difluoro-1,1′-biphenyl
4-*difluoro(3,4,5-trifluorophenoxy)-methyl]-3,5-difluoro-4'-propyl-1,1'-biphenyl
4-[Difluoro(3,4,5-trifluorophenoxy)Methyl]-3,5-difluoro-4'-n-propylbiphenyl, 99%
(3,5-difluoro-4'-propylbiphenyl-4-yl)(difluoro)methyl 3,4,5-trifluorophenyl ether
1,1'-Biphenyl, 4-[difluoro(3,4,5-trifluorophenoxy)methyl]-3,5-difluoro-4'-propyl-
2-[difluoro-(3,4,5-trifluorophenoxy)methyl]-1,3-difluoro-5-(4-pro pylphenyl)benzene
Benzene, 5-[(3,5-difluoro-4'-propyl[1,1'-biphenyl]-4-yl)difluoromethoxy]-1,2,3-trifluoro- | [EINECS(EC#)]
608-462-0 | [Molecular Formula]
C22H15F7O | [MDL Number]
MFCD18451990 | [MOL File]
303186-20-1.mol | [Molecular Weight]
428.343 |
| Chemical Properties | Back Directory | [Melting point ]
42.511℃ (acetic acid ) | [Boiling point ]
431.6±45.0 °C(Predicted) | [density ]
1.332±0.06 g/cm3(Predicted) | [vapor pressure ]
0.013-0.29Pa at 20-50℃ | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Methanol | [form ]
Crystalline | [color ]
White to Almost white | [LogP]
6.5 at 25℃ and pH6.1 | [CAS DataBase Reference]
303186-20-1 |
| Hazard Information | Back Directory | [Chemical Properties]
White Crysstalline | [Uses]
4-*difluoro(3,4,5-trifluorophenoxy)-methyl]-3,5-difluoro-4'-propyl-1,1'-biphenyl is a liquid crystal with a difluoromethyleneoxy linkage group for active-matrix displays | [Preparation]
The preparation of 4-*difluoro(3,4,5-trifluorophenoxy)-methyl]-3,5-difluoro-4'-propyl-1,1'-biphenyl is as follows:In a fluororesin container 3,5-Difluoro-4'-propylbiphenyl-4-thionocarboxylic acid 3,4,5-trifluorophenyl ester (1.65 g, 3.9 mmol), ethyl acetate (10 mL) was added, Further, iodine pentafluoride (IF 5) (0.86 g, 3.9 mmol),And triethylamine · trihydrofluoride salt (NEt3 - 3HF)(0.62 g, 3.9 mmol), and the mixture was stirred at 65 ° C. for 6 hours. After stopping the reaction with an alkali, the organic layer was distilled off under reduced pressure, and the residue was purified by silica gel column chromatography and recrystallization to obtainTo obtain 4- [difluoro- (3,4,5-trifluorophenoxy) -methyl] -3,5-difluoro-4'-propylbiphenyl (1.50 g, 3.5 mmol). The isolation yield was 90%, and the purity was 99.88%.
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