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866641-66-9

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866641-66-9 Structure

866641-66-9 Structure
IdentificationBack Directory
[Name]

(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
[CAS]

866641-66-9
[Synonyms]

JohnPhos Au(MeCN)SbF6
2-(Di-t-butylphosphino)biphenyl(acetonitrile)gold(I) hexafluoroantiMonate, 99%
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
(Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(1+) hexafluoroantimonate
2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99%
[Molecular Formula]

C22H30AuF6NPSb
[MDL Number]

MFCD11045449
[MOL File]

866641-66-9.mol
Chemical PropertiesBack Directory
[Melting point ]

198-203 °C (D)
[form ]

Powder
[color ]

white to off-white
[Sensitive ]

air sensitive, moisture sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H302+H332-H411
[Precautionary statements ]

P273-P301+P312+P330-P304+P340+P312
[Hazard Codes ]

Xn,N
[Risk Statements ]

20/22-51/53
[Safety Statements ]

61
[RIDADR ]

UN 3077 9/PG 3
Questions And AnswerBack Directory
[Reaction]

  1. Gold catalyst used in the regio-and stereoselective synthesis of functionalized benzo[b]oxepines.
  2. Gold catalyst used in the cyclization reactions of o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas.
  3. Gold catalyst used in the cycloisomerization of 1,7-enyne esters to structurally diverse cis-tetrahydropyridin-4-yl ketones.
  4. Catalyst used in the synthesis of coumarin-containing natural products.
  5. Catalyst used in the synthesis of benzo[4,5]imidazo[1,2-a]quinazolinones.
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