TriMethyl(broModifluoroMethyl)silane
- CAS No.
- 115262-01-6
- Chemical Name:
- TriMethyl(broModifluoroMethyl)silane
- Synonyms
- (BroModifluoroMethyl)triMethylsilane;(Bromodifluoromethyl);Difluorobromomethylsilane;Bromodifluoro(trimethylsilyl)methane;TriMethyl(broModifluoroMethyl)silane;Silane, (bromodifluoromethyl)trimethyl-;(Bromodifluoromethyl)trimethylsilane >Trimethyl(bromodifluoromethyl)silane 97%;(Bromodifluoromethyl)trimethylsilane 98%;(Bromodifluoromethyl)trimethylsilane, 98+%
- CBNumber:
- CB02611493
- Molecular Formula:
- C4H9BrF2Si
- Molecular Weight:
- 203.1
- MDL Number:
- MFCD18641931
- MOL File:
- 115262-01-6.mol
- MSDS File:
- SDS
Boiling point | 108°C(lit.) |
---|---|
Density | 1.306 |
refractive index | n/D1.407 |
Flash point | 46℃ |
storage temp. | -20°C |
form | liquid |
color | clear |
InChIKey | WDZVWBWAUSUTTO-UHFFFAOYSA-N |
CAS DataBase Reference | 115262-01-6 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H226-H315-H319-H335 | |||||||||
Precautionary statements | P210-P302+P352-P305+P351+P338 | |||||||||
Risk Statements | 11 | |||||||||
Safety Statements | 24/25 | |||||||||
RIDADR | UN 1993C 3 / PGIII | |||||||||
TSCA | No | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
TriMethyl(broModifluoroMethyl)silane price More Price(36)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 808601 | (Bromodifluoromethyl) 98% | 115262-01-6 | 1g | $118 | 2023-01-07 | Buy |
TCI Chemical | B4325 | (Bromodifluoromethyl)trimethylsilane >98.0%(GC) | 115262-01-6 | 1g | $93 | 2024-03-01 | Buy |
TCI Chemical | B4325 | (Bromodifluoromethyl)trimethylsilane >98.0%(GC) | 115262-01-6 | 5g | $281 | 2024-03-01 | Buy |
TRC | T895825 | Trimethyl(bromodifluoromethyl)silane | 115262-01-6 | 100mg | $60 | 2021-12-16 | Buy |
Biosynth Carbosynth | FB60402 | (Bromodifluoromethyl)trimethylsilane | 115262-01-6 | 500mg | $60 | 2021-12-16 | Buy |
TriMethyl(broModifluoroMethyl)silane Chemical Properties,Uses,Production
Uses
Novel difluorocarbene source for the efficient difluoromethylenation of alkenes/alkynes and difluoromethylation of O-, S-, and N-nucleophiles.
Uses
Trimethyl(bromodifluoromethyl)silane can be used as neuroactive steroids.
Uses
As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.
Reactions
(1) Difluoromethylenation of TMSCN.
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(2) Difluoromethylenation of benzyl and alkylzinc halides.
Ref. Org. Lett. 2013, 15, 917 – 919.
(3) Fluorination aminocarbonylation of aldehydes
Ref. Angew. Chem. Int. Ed. 2022, e202115467
General Description
(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert–Prakash reagent) and BBr3 undergoes fast halogen–exchange reaction to form MSCF2Br.
References
[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
TriMethyl(broModifluoroMethyl)silane Preparation Products And Raw materials
Raw materials
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Preparation Products
TriMethyl(broModifluoroMethyl)silane Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 11013 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2169 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
Allfluoro pharmaceutical co. ltd. | 021-26137118 +8615821363818 | sales@allfluoro.com | China | 5791 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
View Lastest Price from TriMethyl(broModifluoroMethyl)silane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-05-10 | TriMethyl(broModifluoroMethyl)silane
115262-01-6
|
US $0.10-0.10 / kg | 0.004999999888241291kg | 99.99% | 20 tons | Zibo Hangyu Biotechnology Development Co., Ltd | ||
2022-10-10 | TriMethyl(broModifluoroMethyl)silane
115262-01-6
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
2021-07-13 | (Bromodifluoromethyl)trimethylsilane
115262-01-6
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
- TriMethyl(broModifluoroMethyl)silane
115262-01-6
- US $0.10-0.10 / kg
- 99.99%
- Zibo Hangyu Biotechnology Development Co., Ltd
- TriMethyl(broModifluoroMethyl)silane
115262-01-6
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- (Bromodifluoromethyl)trimethylsilane
115262-01-6
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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