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Piperonyl acetone

Piperonyl acetone structure

CAS No.: 55418-52-5

Chemical Name:: Piperonyl acetone

Synonyms: DULCINYL;4-(benzo[d][1,3]dioxol-5-yl)butan-2-one;PIPERONYLACETONE;FEMA 2701;HELIOTROPYL ACETONE;Piperonylacetone>Piperonyl acetone USP/EP/BP;4-(3,4-methylenedioxyphenyl)-2;3,4-METHYLENEDIOXYBENZYL ACETONE;4-(1,3-benzodioxol-5-yl)-2-butanon

CBNumber:: CB0328014

Molecular Formula:: C11H12O3

Molecular Weight:: 192.21

MDL Number:: MFCD00016910

MOL File:: 55418-52-5.mol

MSDS File:: SDS

Last updated:2023-08-24 17:20:48

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Piperonyl acetone Properties

Melting point	49-54 °C(lit.)
Boiling point	176 °C17 mm Hg(lit.)
Density	1.175±0.06 g/cm3(Predicted)
refractive index	1.52-1.522
FEMA	2701 \| 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
Flash point	>230 °F
storage temp.	4°C
solubility	Chloroform (Slightly), DMSO (Slightly)
form	Solid
color	Colourless crystals.
Odor	at 10.00 % in dipropylene glycol. sweet raspberry heliotrope powdery cotton candy
Odor Type	floral
JECFA Number	2048
BRN	169843
InChIKey	TZJLGGWGVLADDN-UHFFFAOYSA-N
LogP	1.53
Substances Added to Food (formerly EAFUS)	4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
CAS DataBase Reference	55418-52-5(CAS DataBase Reference)
FDA UNII	081VVC9H34
NIST Chemistry Reference	4-(3,4-Methylenedioxyphenyl)-2-butanone(55418-52-5)
EPA Substance Registry System	2-Butanone, 4-(1,3-benzodioxol-5-yl)- (55418-52-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

Safety Statements

22-24/25

WGK Germany

TSCA

Yes

HS Code

2914.19.0000

Toxicity

The acute oral LD₅₀ value in rats was reported as 4Og/kg and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Wohl, 1974).

NFPA 704

	1
0		0

Piperonyl acetone price More Price(17)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	S114162	4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE Aldrich	55418-52-5	100mg	$179	2024-03-01	Buy
TCI Chemical	P1089	Piperonylacetone >98.0%(GC)	55418-52-5	25g	$123	2024-03-01	Buy
Alfa Aesar	L06258	4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%	55418-52-5	5g	$42.65	2024-03-01	Buy
Alfa Aesar	L06258	4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%	55418-52-5	25g	$153.65	2024-03-01	Buy
TRC	P475345	PiperonylAcetone	55418-52-5	2.5g	$75	2021-12-16	Buy

Product number	Packaging	Price	Buy
S114162	100mg	$179	Buy
P1089	25g	$123	Buy
L06258	5g	$42.65	Buy
L06258	25g	$153.65	Buy
P475345	2.5g	$75	Buy

Piperonyl acetone Chemical Properties,Uses,Production

Description

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor. May be prepared by condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst.

Chemical Properties

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor reminiscent of raspberry, cotton candy (i.e., candy floss) with a cassie, heliotrope association.

Occurrence

Has apparently not been reported to occur in nature.

Preparation

By condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst

Definition

ChEBI: 4-(3,4-Methylenedioxyphenyl)-2-butanone is a member of benzodioxoles.

Taste threshold values

Taste characteristics at 40 ppm: sweet, berry-like with spicy, jamy nuances

Metabolism

The oxygen-aromatic carbon link of aromatic ethers is generally biologically stable, and possible metabolites include the p-hydroxy derivative of the ether, the phenol or the p-hydroxyphenol (Williams, 1959). Ketones are not readily metabolized in the body. As a derivative of 2-butanone, piperonyl acetone might be expected to be partially reduced to the secondary alcohol and excreted as the glucuronide (Williams, 1959), since Saneyoshi (1911) isolated the glucuronide of 2-butanol from the urine of rabbits receiving methyl ethyl ketone.

Piperonyl acetone synthesis

Synthesis of Piperonyl acetone from Protocatechualdehyde

Piperonyl acetone Preparation Products And Raw materials

Raw materials

2-Butanone, 4-(6-iodo-1,3-benzodioxol-5-yl)- 5(2H)-Isoxazolone, 4-(1,3-benzodioxol-5-ylmethyl)-3-methyl- (E)-4-(benzo[d][1,3]dioxol-6-yl)but-3-en-2-one Piperonyl alcohol Sulfuric acid

Ethyl acetate Methyl vinyl ketone Ethanol 3,4-METHYLENEDIOXYPHENYLBORONIC ACID Acetone

Piperonyl aldehyde Protocatechualdehyde

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Preparation Products

3,4-Methylenedioxyacetophenone

Piperonyl acetone Suppliers

Global( 138)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12471	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	19892	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-89586680 +86-18192503167	1026@dideu.com	China	9126	58
Guangzhou TongYi biochemistry technology Co.,LTD	+8613073028829	mack@tongyon.com	China	2996	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Hubei Jusheng Technology Co.,Ltd.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
TargetMol Chemicals Inc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Shaanxi Dideu Medichem Co. Ltd	58
Guangzhou TongYi biochemistry technology Co.,LTD	58
Labnetwork lnc.	58

View Lastest Price from Piperonyl acetone manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-08-24	Piperonyl acetone 55418-52-5	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2021-08-12	Piperonyl acetone 55418-52-5	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2021-07-02	Piperonylacetone 55418-52-5	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

Piperonyl acetone
55418-52-5
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Piperonyl acetone
55418-52-5
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

Piperonylacetone
55418-52-5
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

Piperonyl acetone Spectrum

Piperonyl acetone(55418-52-5)MS Piperonyl acetone(55418-52-5)¹HNMR Piperonyl acetone(55418-52-5)¹³CNMR Piperonyl acetone(55418-52-5)IR1 Piperonyl acetone(55418-52-5)IR2

55418-52-5(Piperonyl acetone)Related Search:

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Piperonyl aldehyde PIPERONYL METHYL KETONE 5-[3,4(METHYLENEDIOXY)PHENYL]-1,3-CYCLOHEXANEDIONE

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2-Butanone, 4-(1,3-benzodioxol-5-yl)- 4-(1,3-benzodioxol-5-yl)-2-butanon FEMA 2701 HELIOTROPYL ACETONE 3,4-METHYLENEDIOXYBENZYL ACETONE 4-BENZO[1,3]DIOXOL-5-YL-BUTAN-2-ONE 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE 4-(3,4-METHYLENDIOXYPHENYL)-2-BUTANONE 4-(1,3-BENZODIOXOL-5-YL)-2-BUTANONE 4-(1,3-Benzodioxol-5-yl)-2-butanone~3,4-(Methylenedioxy)benzylacetone 4-(1,3-benzodioxol-5-yl)butan-2-one 4-(3,4-methylenedioxyphenyl)-2 2-BUTANONE,4-(3,4-METHYLENEDIOXYPHENYL)- 4-(1,3-Benzodioxol-5-yl)butan-2-on 3 4-METHYLENEDIOXYBENZYL ACETONE 97% 4-[3,4-(Methylenebisoxy)phenyl]butan-2-one 4-(1,3-Benzodioxol-5-yl)-2-butanone 4-(3,4-Methylenedioxyphenyl)-2-butanone 4-(2H-1,3-benzodioxol-5-yl)butan-2-one Piperonylacetone> Piperonyl acetone USP/EP/BP Factory supply Piperonyl acetone CAS 55418-52-5 high quality PIPERONYLACETONE DULCINYL 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one 55418-52-5 Cd1H12O3 Aromatic Ketones (substituted)