DIETHYL (2-METHYLALLYL)PHOSPHONATE 97

CAS No.
51533-70-1
Chemical Name:
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97
Synonyms
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97;Diethyl (2-methylallyl)phosphonate 97%;3-diethoxyphosphoryl-2-methylprop-1-ene;Diethyl P-(2-methyl-2-propen-1-yl)phosphonate;Phosphonic acid, P-(2-methyl-2-propen-1-yl)-, diethyl ester
CBNumber:
CB0505196
Molecular Formula:
C8H17O3P
Molecular Weight:
192.19
MDL Number:
MFCD05664300
MOL File:
51533-70-1.mol
MSDS File:
SDS
Last updated:2022-08-15 17:37:31

DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Properties

Boiling point 62 °C/0.1 mmHg (lit.)
Density 1.013 g/mL at 25 °C (lit.)
refractive index n20/D 1.4380(lit.)
Flash point >230 °F

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
Hazard Codes  Xi
Risk Statements  36
Safety Statements  26
WGK Germany  3

DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 593095 Diethyl (2-methylallyl)phosphonate 97% 51533-70-1 1g $81.2 2023-06-20 Buy
American Custom Chemicals Corporation CHM0157031 DIETHYL (2-METHYLALLYL)PHOSPHONATE 95.00% 51533-70-1 1G $636.81 2021-12-16 Buy
Product number Packaging Price Buy
593095 1g $81.2 Buy
CHM0157031 1G $636.81 Buy

DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Chemical Properties,Uses,Production

Uses

Diethyl (2-methylallyl)phosphonate can be used as a reagent in the Horner-Wadsworth-Emmons reaction to form conjugated carbon–carbon double bonds.
It can also be used as a reactant for:

  • Enantioselective total synthesis of 10-isocyano-4-cadinene as antifouling agent.
  • Regiospecific preparation of 4-oxo-2-alkenylphosphonates (OAP) via silylation followed by Friedel-Crafts acylation and isomerization. OAP can serve as building blocks for the construction of polyethylenic chains.
  • The synthesis of azaphosphone as a potent analgesic/anti-inflammatory agents.

General Description

Diethyl (2-methylallyl)phosphonate is an organophosphorous compound. It participates in the synthesis of α-aminophosphonate derivatives and azaphosphones. The analgesic/antiinflammatory properties of these derivatives were evaluated.

DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Preparation Products And Raw materials

DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Suppliers

Global( 9)Suppliers
Supplier Tel Email Country ProdList Advantage
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44700 61
Shanghai Hanhong Scientific Co.,Ltd. 021-021-64543801 13764082696 2355241799@qq.com China 42982 64
Tianjin Olefin Pharmaceutical Co., Ltd. 18202662021 2211422945@qq.com China 270 56
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Anyang Hongmeng New Materials Co., Ltd 0372-19588588067 19588588067 19588588067@163.com China 11541 58
Baoji Didu Pharmaceutical and Chemical Co., Ltd 17691182729 15991417702 1065@dideu.com China 10010 58
Diethyl (2-methylallyl)phosphonate 97% DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 3-diethoxyphosphoryl-2-methylprop-1-ene Phosphonic acid, P-(2-methyl-2-propen-1-yl)-, diethyl ester Diethyl P-(2-methyl-2-propen-1-yl)phosphonate 51533-70-1 C2H5O2POCH2CCH2CH3 C-C Bond Formation Horner-Wadsworth-Emmons Reagents Olefination