ChemicalBook >> CAS DataBase List >>3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

CAS No.
2386-87-0
Chemical Name:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Synonyms
2021P;3,4-EPOXYCYCLOHEXYLMETHYL;erl-4221;UVR-6110;7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID;ut632;HS-21;EP6110;ERL-4211;3,4-EpoxycycL
CBNumber:
CB1258622
Molecular Formula:
C14H20O4
Molecular Weight:
252.31
MDL Number:
MFCD00440900
MOL File:
2386-87-0.mol
MSDS File:
SDS
Last updated:2023-12-22 19:40:13

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Properties

Melting point −37 °C(lit.)
Boiling point 355.49°C (rough estimate)
Density 1.17 g/mL at 25 °C(lit.)
vapor pressure 0.002Pa at 25℃
refractive index n20/D 1.498(lit.)
Flash point 245 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Dichloromethane (Slightly)
pka 4.61±0.20(Predicted)
form Oil
color Colourless
Specific Gravity 1.170
Water Solubility 13.85g/L at 20.2℃
InChIKey NHJIDZUQMHKGRE-UHFFFAOYSA-N
LogP 1.34 at 20℃
CAS DataBase Reference 2386-87-0(CAS DataBase Reference)
FDA UNII S224DEL3P4
EPA Substance Registry System 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 7-oxabicyclo[4.1.0]hept-3-ylmethyl ester (2386-87-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317-H412
Precautionary statements  P273-P280-P302+P352
Hazard Codes  Xi
Risk Statements  43
Safety Statements  36/37
WGK Germany  1
RTECS  RN7750000
HS Code  29189900
Toxicity LD50 oral in rat: 4490mg/kg

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 407208 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0 50ml $44.34 2024-03-01 Buy
Sigma-Aldrich 407208 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0 250ml $244 2024-03-01 Buy
TRC E585920 3,4-Epoxycyclohexylmethyl3,4-Epoxycyclohexaneca 2386-87-0 1g $40 2021-12-16 Buy
AK Scientific V1829 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0 25g $39 2021-12-16 Buy
Medical Isotopes, Inc. 38139 7-Oxabicyclo[4.1.0]heptan-3-ylmethyl7-oxabicyclo[4.1.0]heptane-3-carboxylate 95+% 2386-87-0 25g $320 2021-12-16 Buy
Product number Packaging Price Buy
407208 50ml $44.34 Buy
407208 250ml $244 Buy
E585920 1g $40 Buy
V1829 25g $39 Buy
38139 25g $320 Buy

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Chemical Properties,Uses,Production

Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate TTA21S is a pale yellow to colorless transparent liquid. Two package and UV cure formulas use TTA21 to create better crosslinks and enhance adhesion. Each molecule creates high cross-linking due to the dual epoxide functionality, which can react with hydroxyl, carboxyl, or amine groups of polymers in the system. End users take advantage of the UV stability and low viscosity compared to other epoxy resins.

Chemical Properties

Pale yellow to colorless transparent liquid

Uses

EEC is an epoxy monomer that can be used as a resin in aerospace, electronics and automobile industries as an adhesive and a composite material.

Uses

This compound can be made by treatment of the corresponding bis-unsaturated ester with peracetic acid. It is used as a reactive diluent, for filament winding, as an acid scavenger, or as a plasticizer. Vapor hazard is slight at ambient temperature because of its moderately high boiling point. Skin contact is to be avoided.

General Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy that can be synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. Its aliphatic backbone and molecular structure provide a number of useful properties such as thermal stability, weatherability, and electrical conductivity.

Flammability and Explosibility

Non flammable

Synthesis

128.17kg of 3,4-epoxycyclohexyl-1-methanol, 312.36kg of 3,4-epoxycyclohexyl-1-methyl carboxylate, 9.61kg of tetrabutoxytitanium were added to the 500L reactor, and reacted at 100°C 7 hours (there is no apparent liquid steaming out at this time, sampling GC detection 3,4-epoxycyclohexyl-1-methanol content≤1.0wt%), stop the reaction; The reaction solution is at 500Pa vacuum, 95 vacuum distillation to remove excess Methyl 3,4-epoxycyclohexyl-1-carboxylate, the concentrated solution was distilled by molecular distillation, vacuum distillation at 2Pa, 144°C under reduced pressure to obtain 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate.
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

2611-00-9
2386-87-0
Synthesis of 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate from 3-Cyclohexenyl 3-cyclohexene 1-carboxylate

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 291)Suppliers
Supplier Tel Email Country ProdList Advantage
EAST STAR BIOTECH (SUZHOU) CO., LTD.
+8617706846989 marketing@eaststarbio.com China 48 58
Nanjing Qiangshan New Material Co.,Ltd.
+86-13951653990 +86-13951653990 jjx35259720@hotmail.com China 27 58
Shanghai Z&T Chemical Co., Ltd
+86-21-33561011 13818804961 Sales@ztchemical.com.cn China 402 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 6000 58
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 18232 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9341 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55

View Lastest Price from 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate pictures 2024-05-15 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0
US $70.00 / kilograms 10kilograms 99 10 Hebei Dangtong Import and export Co LTD
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate pictures 2024-05-15 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0
US $0.00 / KG 1KG ≥99% 1000mt/year Jinan Finer Chemical Co., Ltd
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate pictures 2023-12-23 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
3,4-epoxycyclohexanecarboxylicacid(3,4-epoxycyclohexylmethyl)ester 3,4-epoxycyclohexanemethyl3,4-epoxycyclohexanecarboxylate 3,4-epoxycyclohexylmethyl3,4-epoxycyclo-hexaneca 7-oxabicyclo(4.1.0)heptane-3-carboxylicacid,7-oxabicyclo(4.1.0)hept-3-ylmethy 7-Oxabicyclo[4,1,0]heptane-3-carboxylicacid,7-oxabicyclo[4,1,0]hept-3-ylmethylester 3,4-Epoxycyclohexylmethyl-3,4-epoxycy-clohexane Carboxylate (JR-HS-21) 7-Oxabicyclo[4.1.0]heptan-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate 1,2-Epoxycyclohexane-4-carboxylic acid 1,2-epoxycyclohexane-4-ylmethyl ester 3,4-Epoxy-1-cyclohexanecarboxylic acid (3,4-epoxycyclohexan-1-yl)methyl ester 3,4-Epoxycyclohexane-1-carboxylic acid (3,4-epoxycyclohexane-1-yl)methyl ester 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid 7-oxabicyclo[4.1.0]heptan-3-ylmethyl ester ERL-4211 Cycloaliphatic Epoxide Resin ERL-4221 1-{7-oxabicyclo[4.1.0]heptan-3-ylMethyl}-7-oxabicyclo[4.1.0]heptane-3-carboxylate 3,4-EpoxycyclohexylM :Cycloaliphatic Epoxy 3,4-Epoxycyclohexylmethyl, 3,4-Epoxycyclohexanecarboxylate (UVR-6110,6103,6105,6107) 3'-4'-Epoxycyclohexane)Methyl 3'-4'-Epoxycyclohexyl-carboxylate 3,4-Epoxycyclohexylmethyl, 3,4-Epocyclohexane Carboxylate (UVR-6110,6103,6105,6107) chissonox221monomer ut632 3,4-EPOXYCYCLOHEXYLMETHYL 3',4'-EPOXYCYCLOHEXANECARBOXYLATE 3,4-EPOXYCYCLOHEXYLMETHYL 3,4-EPOXYCYCLOHEXANECARBOXYLATE 3,4-EPOXYCYCLOHEXYLMETHYL-3,4-EPOXYCYCLOHEXYLCARBOXYLATE 7-oxabicyclo[4.1.0]hept-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate EPOXYCYCLOHEXYLMETHYL-EPOXYCYCLO-HEXANECARBOXYLATE 7-OXABICYCLOHEPTANE-3-CARBOXYLICACID,7-OXABICYCLOHEPT-3-YLMETHYLESTER 7-OXABICYCLOHEPTANE-3-CARBOXYLICACID 7-Oxabicyclo(4.1.0)hept-3-ylmethyl-7-oxabicyclo(4.1.0)heptan-3-carboxylat EMBEDDING MEDIUM ERL-4221D 3,4-EpoxycycL 3,4-Epoxycyclohexylmethyl, 3,4-Epoxcyclohexane Carboxylate Uvr-6110 HS-21 Daicel Celloxide 2021 Cycloaliphatic epoxy resin Daicel Celloxide Syna Epoxy 06E (UVR6105, ERL4221D) Syna Epoxy 21 (UVR6110, ERL4221) Syna Epoxy 10 4-epoxycyclohexanecarboxylate 4-Epoxycyclohexylmethyl 3 UVR-6110 erl-4221 3,4-EPOXYCYCLOHEXYLMETHYL 7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID 2021P CAS 2386-87-0 3, 4-Epoxycyclohexylmethyl 3, 4-Epoxycyclo-Hexaneca Uvr-6110 3,4-Epoxycyclohexylmethyl-3’ 3, 4-Epoxycyclo-Hexaneca Uvr-6110 3,4-epoxycyclohexylmethyl 3,4-epoxycyclodecanoate EP6110 2386-87-0 Epoxide Monomers Monomers Polymer Science