2'-Hydroxy-4'-methyl-5'-acetylacetophenone
- CAS No.
- 16475-85-7
- Chemical Name:
- 2'-Hydroxy-4'-methyl-5'-acetylacetophenone
- Synonyms
- 2,4-Diacetyl-5-methylphenol;2'-Hydroxy-4'-methyl-5'-acetylacetophenone;Ethanone, 1,1'-(4-hydroxy-6-methyl-1,3-phenylene)bis- (9CI)
- CBNumber:
- CB22156585
- Molecular Formula:
- C11H12O3
- Molecular Weight:
- 192.21
- MDL Number:
- MOL File:
- 16475-85-7.mol
2'-Hydroxy-4'-methyl-5'-acetylacetophenone Chemical Properties,Uses,Production
Preparation
Preparation by cyclization of 1,1,3,3-tetraacetylpropene (formerly so called methenylbisacetylacetone) (SM) (m.p. 117–118°)
, ? by adding a solution of SM (1 mol) in benzene to a sodium methoxide (4 mol)
or magnesium methoxide (4 mol) solution in methanol and set aside for 24 h (quantitative yields)
; ? on heating of its potassium salt in alcoholic solution for 6–8 h at reflux. SM was prepared by treatment of ethoxymethyleneacetylacetone (m.p. 140–142°) with the potassium salt of acetylacetone in ethanol
.
2'-Hydroxy-4'-methyl-5'-acetylacetophenone Preparation Products And Raw materials
2,4-Diacetyl-5-methylphenol
2'-Hydroxy-4'-methyl-5'-acetylacetophenone
Ethanone, 1,1'-(4-hydroxy-6-methyl-1,3-phenylene)bis- (9CI)
16475-85-7