ChemicalBook >> CAS DataBase List >>SILVER TRIFLUOROMETHANESULFONATE
SILVER TRIFLUOROMETHANESULFONATE
- CAS No.
- 2923-28-6
- Chemical Name:
- SILVER TRIFLUOROMETHANESULFONATE
- Synonyms
- AGOTF;SILVER TRIFLATE;SILVER TRIFLUOROMETHANESULPHONATE;Silver (trifluoromethyl)sulfonate;TRIFLUOROMETHANESULFONIC ACID SILVER SALT;fonate;ver trifL;uoromethanesuL;Silver(I)triflate;Indiumtrifluorometha
- CBNumber:
- CB3157655
- Molecular Formula:
- CAgF3O3S
- Molecular Weight:
- 256.94
- MDL Number:
- MFCD00013226
- MOL File:
- 2923-28-6.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
Melting point | 286 °C (lit.) |
---|---|
storage temp. | Store below +30°C. |
solubility | Methanol (Slightly), Water (Slightly) |
form | Powder |
color | White to light beige |
Water Solubility | Soluble in water and also in most organic solvents. |
Sensitive | Light Sensitive |
Hydrolytic Sensitivity | 6: forms irreversible hydrate |
BRN | 3598402 |
Stability | Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents. |
InChI | InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1 |
InChIKey | QRUBYZBWAOOHSV-UHFFFAOYSA-M |
SMILES | C(F)(F)(F)S([O-])(=O)=O.[Ag+] |
CAS DataBase Reference | 2923-28-6(CAS DataBase Reference) |
FDA UNII | UK2MGY9YSF |
EPA Substance Registry System | Methanesulfonic acid, trifluoro-, silver(1+) salt (2923-28-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H315-H318 | |||||||||
Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P362+P364 | |||||||||
Hazard Codes | Xi,C | |||||||||
Risk Statements | 36/37/38-50-34 | |||||||||
Safety Statements | 26-36-61-45-36/37/39 | |||||||||
RIDADR | 3260 | |||||||||
WGK Germany | 3 | |||||||||
F | 8 | |||||||||
Hazard Note | Corrosive | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
HS Code | 28432900 | |||||||||
NFPA 704 |
|
SILVER TRIFLUOROMETHANESULFONATE price More Price(56)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 8.14325 | Silver trifluoromethanesulfonate for synthesis | 2923-28-6 | 5G | $103 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.14325 | Silver trifluoromethanesulfonate for synthesis | 2923-28-6 | 25g | $342 | 2024-03-01 | Buy |
Sigma-Aldrich | 176435 | Silver trifluoromethanesulfonate ≥99% | 2923-28-6 | 1g | $40.4 | 2024-03-01 | Buy |
Sigma-Aldrich | 176435 | Silver trifluoromethanesulfonate ≥99% | 2923-28-6 | 10g | $122 | 2024-03-01 | Buy |
TCI Chemical | T1331 | Silver Trifluoromethanesulfonate >98.0%(T) | 2923-28-6 | 1g | $28 | 2024-03-01 | Buy |
SILVER TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production
Reactions
- Silver precatalyst for the asymmetric allylation of aldehydes
- Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
- Silver catalyst for the fluorination of boronic acids
- Silver catalyst for the fluorination of functionalized aryl stannanes
- Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
- Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
Chemical Properties
light beige crystalline powder
Uses
Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
General Description
Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.
Purification Methods
Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.]
SILVER TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 396)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Nanjing Sinoda Biological Technology Co., Ltd | +8613401983379 | sales@njmcn.cn | CHINA | 74 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15954 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21687 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9340 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1377 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32715 | 60 |
Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
View Lastest Price from SILVER TRIFLUOROMETHANESULFONATE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-03-10 | SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
|
US $0.00 / KG | 1KG | 99.0% | 1000KG | LY Global chemicals co.,ltd . | ||
2022-10-10 | SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
2022-09-23 | SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
|
US $0.00 / kg | 1kg | 99% | 1000kg | henan kanbei chemical co.,ltd |
- SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
- US $0.00 / KG
- 99.0%
- LY Global chemicals co.,ltd .
- SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
- US $0.00 / kg
- 99%
- henan kanbei chemical co.,ltd
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SILVER TRIFLUOROMETHANESULFONATE
TRIFLUOROMETHANESULFONATE SILVER SALT
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LVER TRIFLUOROMETHANESULFONATE
Silver trifluoroMethanesulfonate,98% (Silver triflate) Ag(CF3SO3)
SILVER TRIFLUOROMETHANESULFONATE FOR SYN
(trifluoroMethylsulfonyloxy)silver, TfOAg
SILVER (I) TRILUOROMETHANE SULFONATE
silver(I) 4-(trifluoroMethyl)benzenesulfonate
Silver trifluoroMethanesulfonate >=99.95% trace Metals basis
Silver trifluoromethanesulfonate purum, >=98.0% (Ag)
trifluoro-methanesulfonicacisilver(1++)salt
Silvertrifluoromethanesulfonate,99%(Silvertriflate)
Methanesulfonic acid, trifluoro-, silver(1+) salt
Silver trifluoromethanesulphonate 99%
Silver trifluormethanesulfonate
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SILVER TRIFLUOROMETHANESULFONATE, 99.95+ %
SILVER TRIFLUOROMETHANESULFONATE, 99+%
Silver(I)triflate
Trifluoromethanesulfonicacidsilver(I)salt
Silvertrifluoromethanesulphonate99%
SILVER TRIFLUOROMETHANESULFONATE (SILVER TRIFLATE)
SILVER TRIFLUOROMETHANESULFOTE
Silver trifluoromethanesulfonate (99.95%-Ag) (Silver triflate)
TRIFLUOROMETHYLSULFONYLOXYSILVER
Indiumtrifluorometha
Silver Trifluoromethanesulfonate (AgOTf)
SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%
silver trifluoromethanesulphonate CHF3O3S.Ag
fonate
uoromethanesuL
ver trifL
Silver trifluoromethanesulfonate, 98%, for synthesis
Powdered silver trifluoromethanesulfonate
Methanesulfonic acid, 1,1,1-trifluoro-, silver(1+) salt (1:1)
SILVER TRIFLUOROMETHANESULFONATE ISO 9001:2015 REACH
Silver Trifluoromethanesulfonate extrapure, 98%
SILVER TRIFLATE
SILVER TRIFLUOROMETHANESULPHONATE
TRIFLUOROMETHANESULFONIC ACID SILVER SALT
Silver (trifluoromethyl)sulfonate
AGOTF
Silver(Ⅰ) trifluorometanesulfonate
SILVER TRIFLATE
Silver trifluoromethanesulfonate
2923-28-6
AgSO3CF3
AgOSO2CF3
CHF3O3SAg