(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester

CAS No.
38734-62-2
Chemical Name:
(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester
Synonyms
Raufloricine;10-Methoxyakuammiline;(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester
CBNumber:
CB42223164
Molecular Formula:
C24H28N2O5
Molecular Weight:
424.48952
MDL Number:
MOL File:
38734-62-2.mol

(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester Properties

Melting point 190-2°C

(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester Chemical Properties,Uses,Production

Description

The root bark of Rauwolfia confertiflora Pichon yields this alkaloid which forms colourless crystals from AcOEt. The base is strongly dextrorotatory with [α]20D + 129° (c l.5, CHCI3). In MeOH, the ultraviolet spectrum exhibits absorption maxima at 225,286 and 310 ffiJ.1. The alkaloid has been shown to be pentacyclic and contains a methoxyl group, an allyl group, a methoxycarbonyl and an acetoxymethyl group.

References

Danieli et ai., Chern. Ind. (Milan), 54, 618 (1972)

(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(16R)-17-Acetyloxy-10-methoxyakuammilan-16-carboxylic acid methyl ester 10-Methoxyakuammiline Raufloricine 38734-62-2