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ChemicalBook >> CAS DataBase List >>(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Structure
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% structure
CAS No.
150971-45-2
Chemical Name:
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms
SL-A116-1;(R)-iPr-MeOBIPHEP;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine);(R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%;(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(+)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
CBNumber:
CB51180977
Molecular Formula:
C26H40O2P2
Molecular Weight:
446.54
MDL Number:
MFCD09753011
MOL File:
150971-45-2.mol
Last updated:2023-04-23 13:52:06
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(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Properties

Boiling point 517.2±50.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color white

SAFETY

Risk and Safety Statements

HS Code  29319090

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 150971-45-2 100mg $96 2024-03-01 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 150971-45-2 500mg $355 2024-03-01 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 150971-45-2 2g $1207 2024-03-01 Buy
Strem Chemicals 15-0654 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 150971-45-2 10g $4824 2024-03-01 Buy
American Custom Chemicals Corporation ING0001295 (R)-(+)-2,2'-BIS(DI-I-PROPYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 150971-45-2 1G $1309.77 2021-12-16 Buy
Product number Packaging Price Buy
15-0654 100mg $96 Buy
15-0654 500mg $355 Buy
15-0654 2g $1207 Buy
15-0654 10g $4824 Buy
ING0001295 1G $1309.77 Buy

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Uses,Production

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.

  1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
  2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
  3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
  4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
  5. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
  6. Rhodium-catalyzed carbonyl Z-dienylation.
  7. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
Reactions of 150971-45-2_1
Reactions of 150971-45-2_2

Chemical Properties

Off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

Global( 24)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39916 58
changzhou huayang technology co., ltd 		+8615250961469 2571773637@qq.com China 9821 58
Suzhou Origin Specialty Chemicals Co., Ltd. 		+86-512-68662322 +86-17312436797 hanqun@origsc.com China 788 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44700 61
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-0371-65511006 18625597674 sales@kingorgchem.com China 950 55
Supplier Advantage
career henan chemical co 		58
Chongqing Chemdad Co., Ltd 		58
changzhou huayang technology co., ltd 		58
Suzhou Origin Specialty Chemicals Co., Ltd. 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55

View Lastest Price from (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% pictures 2019-08-09 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
150971-45-2
 US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co

150971-45-2((R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%)Related Search:

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(S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-TolBINAP (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
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(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine) (R)-iPr-MeOBIPHEP, SL-A116-1, (R)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl (R)-iPr-MeOBIPHEP SL-A116-1 (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97% (R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)- (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl 150971-45-2 Chiral Phosphine MeOBIPHEP Series