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Benzo-15-crown-5

CAS No.
14098-44-3
Chemical Name:
Benzo-15-crown-5
Synonyms
2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine;denzo15c5;benzo15c5;BENZO-15-CROWN-5;Benzo-15-crown-5,99%;Monobenzo-15-crown-5;Benzo-15-crown-5,97%;2,3-Benzo-15-crown-5;Benzo-15-crown-5,>98%;BENZO-15-CROWN 5-ETHER
CBNumber:
CB5223772
Molecular Formula:
C14H20O5
Molecular Weight:
268.31
MDL Number:
MFCD00005945
MOL File:
14098-44-3.mol
MSDS File:
SDS
Last updated:2023-10-25 17:20:07

Benzo-15-crown-5 Properties

Melting point 78-80 °C (lit.)
Boiling point 371.47°C (rough estimate)
Density 1.1846 (rough estimate)
refractive index 1.4825 (estimate)
storage temp. Inert atmosphere,Room Temperature
form Powder or Flakes
color Almost white to light gray
Water Solubility partially soluble
Sensitive Hygroscopic
BRN 1624106
InChIKey DSFHXKRFDFROER-UHFFFAOYSA-N
CAS DataBase Reference 14098-44-3(CAS DataBase Reference)
EWG's Food Scores 1
NIST Chemistry Reference Bis(1,4,7,10,13-benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-)(14098-44-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
RTECS  DI5400000
3-10
Hazard Note  Irritant
HS Code  29329995
NFPA 704
1
2

Benzo-15-crown-5 price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 282790 Benzo-15-crown-5 98% 14098-44-3 5g $157 2024-03-01 Buy
TCI Chemical B1154 Benzo-15-crown 5-Ether >98.0%(GC) 14098-44-3 1g $71 2024-03-01 Buy
TCI Chemical B1154 Benzo-15-crown 5-Ether >98.0%(GC) 14098-44-3 5g $313 2024-03-01 Buy
Alfa Aesar A16011 Benzo-15-crown-5, 98% 14098-44-3 1g $39.65 2024-03-01 Buy
Alfa Aesar A16011 Benzo-15-crown-5, 98% 14098-44-3 5g $149 2024-03-01 Buy
Product number Packaging Price Buy
282790 5g $157 Buy
B1154 1g $71 Buy
B1154 5g $313 Buy
A16011 1g $39.65 Buy
A16011 5g $149 Buy

Benzo-15-crown-5 Chemical Properties,Uses,Production

Chemical Properties

ALMOST WHITE TO LIGHT GREY POWDER OR FLAKES

Uses

Benzo-15-crown-5 is used in synthetic chemistry. It plays a major role and involved in complexation through ether oxygen. It is used in phase-transfer catalyst system. It is involved in 'Host-Guest' chemistry to identify the move of essential elements in the body. It can play the part of very complicated biological reactions such as enzyme functions, which finds application in the development of new pharmaceuticals.

Application

Benzo-15-crown-5 can be used for sol-gel material extraction to separate lithium isotopes, for making static detection sensors for formic acid gases, and as metal ion complexing agent and phase transfer reagent.

Preparation

synthesis of Benzo-15-crown-5: benzo-15-crown-5 can be produced using Williamson synthesis reaction, featured by interaction between catechol (orto-dihydroxybenzene) and tetraethylene glycol dichloride (1,10-dichloro-3,6,9-trioxadecane) over sodium hydroxide in the n-butanol media (30-h inertatmosphere boiling). The yield of benzo-15-crown-5 produced by this method is 62%, with the basic substance's mass fraction of 95%.
Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives

Definition

ChEBI: Benzo-15-crown-5 is a crown ether that is 15-crown-5 ortho-fused to a benzene ring.

638-56-2
120-80-9
14098-44-3
Synthesis of Benzo-15-crown-5 from DIETHYLENE GLYCOL BIS(2-CHLOROETHYL) ETHER and Catechol
Global( 237)Suppliers
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Ningxia LabsChem Co., Ltd.
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CONIER CHEM AND PHARMA LIMITED
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View Lastest Price from Benzo-15-crown-5 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzo-15-crown-5 pictures 2023-10-26 Benzo-15-crown-5
14098-44-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Benzo-15-crown-5 pictures 2023-10-21 Benzo-15-crown-5
14098-44-3
US $40.00-40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Benzo-15-crown-5 pictures 2023-09-06 Benzo-15-crown-5
14098-44-3
US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
  • Benzo-15-crown-5 pictures
  • Benzo-15-crown-5
    14098-44-3
  • US $40.00-40.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
  • Benzo-15-crown-5 pictures
  • Benzo-15-crown-5
    14098-44-3
  • US $0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
Benzo-15-crown-5, 99% 2.5GR CROWN ETHER/BENZO-15-CROWN-5 FOR SYNTHES 2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-15,17,19-triene 1,2-[Oxybis(ethyleneoxyethyleneoxy)]benzene 2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene 6,7,9,10,12,13,15,16-Octahydro-5,8,11,14,17-pentaoxa-5H-benzocyclopentadecene Benzo-15-crown-5,99% denzo15c5 Monobenzo-15-crown-5 2,3-BENZO-1,4,7,10,13-PENTAOXACYCLOPENTADEC-2-ENE 2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN 1,4,7,10,13-PENTAOXA(13)ORTHOCYCLOPHANE BENZO-15-CROWN-5 BENZO-15-CROWN 5-ETHER CROWN ETHER/BENZO-15-CROWN-5 Benzo-15-crown-5,97% Crown ether/Benzo-15-crown-5 for synthesis 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro- 2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine 2,3-benzo-1,4,7,10,13-pentaoxacyclopentadecane 2,3-Benzo-15-crown-5 4,7,10,13-Benzopentaoxacyclopentadecin,2,3,5,6,8,9,11,12-octahydro-1 7,10,13-benzopentaoxacyclopentadecin,2,3,5,6,8,9,11,12-octahydro-4 Benzo[6]1,4,7,10,13-pentaoxacyclopentadecane benzo15c5 Benzo-15-crown 5-Ether > Benzo-15-crown-5, 98%, reagent grade Benzo-15-crown-5,>98% 14098-44-3 Benzo-15-crown-5 2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(19),15,17-triene 2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine Benzo -15- crown ether -5 Benzo-15-crown-5(2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin) 14098-44-3 C14H20O5 Synthetic Reagents Chelation/Complexation Compounds Crown Ethers Macrocycles for Host-Guest Chemistry crown ether Crown Ethers Functional Materials Macrocycles for Host-Guest Chemistry Chelation/Complexation Compounds Crown Ethers Synthetic Reagents