(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester
- CAS No.
- 14509-92-3
- Chemical Name:
- (3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester
- Synonyms
- Mitraciliatin;Mitraciliatine;(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester;Indolo[2,3-a]quinolizine-2-acetic acid, 3-ethyl-1,2,3,4,6,7,12,12b-octahydro-8-methoxy-α-(methoxymethylene)-, methyl ester, (αE,2S,3R,12bR)-
- CBNumber:
- CB52395352
- Molecular Formula:
- C23H30N2O4
- Molecular Weight:
- 398.5
- MDL Number:
- MOL File:
- 14509-92-3.mol
Last updated:2022-12-21 16:56:50
Melting point | 140-141 °C |
---|---|
Boiling point | 560.3±50.0 °C(Predicted) |
Density | 1.22±0.1 g/cm3(Predicted) |
pka | 18.35±0.60(Predicted) |
FDA UNII | IE9LY4S85X |
(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester Chemical Properties,Uses,Production
Description
Mitragyna ciliata Aubr. et Pellegr. yields this carboline alkaloid which may be purified by crystallization from Et20-light petroleum when it forms small, colourless crystals. The ultraviolet spectrum exhibits absorption maxima at 228 and 292.4 mil with shoulders at 248.8 and 284 mil. The base may be charac_x0002_terized as the perchlorate which forms light yellow prisms from EtOH-Et20, m.p.229-230°C.
References
Beckett, Shellard, Tackie., J. Pharm. Pharmacal. Suppl., 15, 166T (1963)
Beckett, Tackie., ibid, 15, 267T (1963)
Absolute configuration:
Lee, Trager, Beckett., Tetrahedron, 23, 375 (1967)
(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester Suppliers
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(3β,16E)-16,17-Didehydro-9,17-dimethoxycorynan-16-carboxylic acid methyl ester
Mitraciliatin
Mitraciliatine
Indolo[2,3-a]quinolizine-2-acetic acid, 3-ethyl-1,2,3,4,6,7,12,12b-octahydro-8-methoxy-α-(methoxymethylene)-, methyl ester, (αE,2S,3R,12bR)-
14509-92-3