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GOLD(III) BROMIDE

CAS No.
10294-28-7
Chemical Name:
GOLD(III) BROMIDE
Synonyms
GOLD BROMIDE;Auric bromide;d(III) bromide;GOLD TRIBROMIDE;GOLD(III) BROMIDE;goldbromide(aubr3);digold hexabroMide;Gold(III) tribromide;GOLD(III) BROMIDE, 99.9%;Gold(III) bromide Hydrate
CBNumber:
CB7173020
Molecular Formula:
AuBr3
Molecular Weight:
436.68
MDL Number:
MFCD00014171
MOL File:
10294-28-7.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

GOLD(III) BROMIDE Properties

Melting point 160°C (dec.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility H2O: slightly soluble(lit.)
form Powder
color orange to brown
Water Solubility Slightly soluble in water.
Sensitive moisture sensitive
CAS DataBase Reference 10294-28-7(CAS DataBase Reference)
FDA UNII 4PJV3VH75Y
EPA Substance Registry System Gold bromide (AuBr3) (10294-28-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3260 8/PG 3
WGK Germany  3
8-10-23
TSCA  Yes
HazardClass  8
PackingGroup  III
NFPA 704
0
3 0

GOLD(III) BROMIDE price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 398470 Gold(III) bromide 99.9% trace metals basis 10294-28-7 1g $163 2024-03-01 Buy
Sigma-Aldrich 398470 Gold(III) bromide 99.9% trace metals basis 10294-28-7 5g $701 2024-03-01 Buy
Alfa Aesar A19514 Gold(III) bromide, 99% 10294-28-7 1g $260 2024-03-01 Buy
Alfa Aesar 012162 Gold(III) bromide, Premion?, 99.99% (metals basis), Au 44.6% min 10294-28-7 1g $148 2024-03-01 Buy
Strem Chemicals 93-7905 Gold(III) bromide, anhydrous, 99% (99.9+%-Au) 10294-28-7 1g $123 2024-03-01 Buy
Product number Packaging Price Buy
398470 1g $163 Buy
398470 5g $701 Buy
A19514 1g $260 Buy
012162 1g $148 Buy
93-7905 1g $123 Buy

GOLD(III) BROMIDE Chemical Properties,Uses,Production

Chemical Properties

Yellowish-gray mass. Decomposes at approximately 165C. Insoluble in water.

Uses

Analysis (testing for alkaloids, spermatic fluid), medicine.

Uses

Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.

Definition

Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.

Purification Methods

Purify it by adding pure Br2 to the dark powder, securely stopper the container, warm a little and shake while keeping away from light for ca 48hours. Remove the stopper and place it over NaOH until free Br2 is no longer in the apparatus (48-60hours). The bright yellow needles of the tribromide are stable over NaOH in the dark. It is soluble in H2O and in EtOH where it is slowly reduced. Keep it in a cooled, closed container and protect it from light as decomposition causes free gold to be formed. Aurobromic acid can be obtained by adding the calculated amount of conc HBr to AuBr3 (actually Au2Br6) until all dissolves, whereby the acid crystallises out as HAuBr4.5H2O; a deliquescent solid soluble in EtOH with m ca 27o, and store it as above. [Gibson & Colles J Chem Soc 2411 1931, Burawoy & Gibson J Chem Soc 217 1935, Burawoy & Gibson J Chem Soc 219 1935.]

GOLD(III) BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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