(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol

CAS No.
39027-76-4
Chemical Name:
(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol
Synonyms
Poranthericine;(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol;Pyrido[2,1,6-de]quinolizin-2-ol, 1-ethyldodecahydro-9a-methyl-, [1S-(1α,2β,3aβ,6aβ,9aβ)]- (9CI)
CBNumber:
CB72329696
Molecular Formula:
C15H27NO
Molecular Weight:
237.38098
MDL Number:
MOL File:
39027-76-4.mol

(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol Properties

Boiling point 350.1±17.0 °C(Predicted)
Density 1.04±0.1 g/cm3(Predicted)
pka 14.88±0.60(Predicted)

(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol Chemical Properties,Uses,Production

Description

A minor base from Poranthera corymbosa, this alkaloid is a colourless oil which is laevorotatory with [α]D - 20° (c 0.45, CHC13). The hydrobromide is crystalline, m.p. 308°C (dec.) and the O-acetyl derivative occurs naturally in the same source (q.v.).

References

Denne et al., Tetrahedron Lett., 1767 (1972)

(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,3aβ,6aβ)-Dodecahydro-1α-ethyl-9aβ-methylpyrido[2,1,6-de]quinolizin-2β-ol Poranthericine Pyrido[2,1,6-de]quinolizin-2-ol, 1-ethyldodecahydro-9a-methyl-, [1S-(1α,2β,3aβ,6aβ,9aβ)]- (9CI) 39027-76-4