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1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid

CAS No.
90-20-0
Chemical Name:
1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid
Synonyms
H Acids;c.i.35570;kyselinah;1-Naphthol-8-amino-3,6-disulfonicacid;1-Amino-8-naphthol-3,6-disulphonicacid;8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID;1-AMINO-8-NAPHTHOL-3,6-DISULFONIC ACID;kyselina8-amino-1-naftol-3,6-disulfonova;kyselina1-amino-8-naftol-3,6-disulfonova;1-Amino-8-hydroxy-3,6-disulfonaphthalene
CBNumber:
CB7306275
Molecular Formula:
C10H9NO7S2
Molecular Weight:
319.31
MDL Number:
MFCD00035728
MOL File:
90-20-0.mol
MSDS File:
SDS
Last updated:2023-11-07 17:00:51

1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid Properties

Melting point >300 °C(lit.)
Density 1.6832 (rough estimate)
refractive index 1.7640 (estimate)
solubility DMSO (Slightly, Heated), Methanol (Slightly), Water (Slightly)
form Solid
pka -0.95±0.40(Predicted)
color Light Beige to Beige
CAS DataBase Reference 90-20-0(CAS DataBase Reference)
FDA UNII 4WUM31ES4U
EPA Substance Registry System 2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy- (90-20-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H332-H315-H319-H335
Precautionary statements  P271-P260-P280
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  2922210060

1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Matrix Scientific 074462 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid 95+% 90-20-0 5g $25 2021-12-16 Buy
AK Scientific K640 4-Amino-5-hydroxy-2,7-naphthalenedisulfonicacid 90-20-0 25g $38 2021-12-16 Buy
Biosynth Carbosynth FA40913 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid 90-20-0 10g $65 2021-12-16 Buy
Matrix Scientific 074462 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid 95+% 90-20-0 25g $75 2021-12-16 Buy
Biosynth Carbosynth FA40913 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid 90-20-0 25g $120 2021-12-16 Buy
Product number Packaging Price Buy
074462 5g $25 Buy
K640 25g $38 Buy
FA40913 10g $65 Buy
074462 25g $75 Buy
FA40913 25g $120 Buy

1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid Chemical Properties,Uses,Production

Chemical Properties

1-Amino-8-hydroxynaphthalene-3,6-disulfonic acid [90-20-0]. (4-amino-5-hydroxynaphthalene-2,7-disulfonic acid), H acid, C10H9NO7S2, Mr 319.3, is usually isolated as its monosodium salt [5460-09-3], a gray powder that is slightly soluble in cold water and readily soluble in hot water; the disodium salt is very soluble in water. With diazo compounds, H acid couples ortho to the amino group under acid conditions and ortho to the hydroxyl group under alkaline conditions. Bisazo derivatives are formed by stepwise acid and alkaline coupling, with the much slower acid coupling being performed first.

Uses

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic Acid is useful for preparing reactive dyes.

Purification Methods

A slightly alkaline solution of Na2CO3 (ca 22g) in water (litmus) is added to a solution of 100g of the dry acid in 750mL of hot distilled water, followed by 5g of activated charcoal and 5g of Celite. The suspension is stirred for 10minutes and filtered by suction. The acid is then precipitated by adding ca 40mL of conc HCl (solution is blue to Congo Red), then filter it by suction through a shark skin filter circular sheet (or hardened filter paper) and wash it with 100mL of distilled water. The purification process is repeated. The acid is dried overnight in an oven at 60o and stored in a dark bottle The diethylamine salt has m 306-307o(dec, from aqueous EtOH). [Post & Moore Anal Chem 31 1872 1959]. [Beilstein 14 H 840, 14 I 758, 14 II 502, 14 III 2292, 14 IV 2824.]

91-20-3
90-20-0
Synthesis of 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid from Naphthalene
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Changzhou waston chemical technology Co.,Ltd
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View Lastest Price from 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid pictures 2023-10-09 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid
90-20-0
US $0.00 / kg 1kg 98% according to customer's requirements Changzhou waston chemical technology Co.,Ltd
1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid pictures 2023-04-25 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid
90-20-0
US $50.00 / kg 1kg 99% 100 tons Hebei Duling International Trade Co. LTD
1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid  pictures 2022-07-29 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid
90-20-0
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
4-amino-5-hydroxy-7-naphthalenedisulfonicacid 7-Naphthalenedisulfonicacid,4-amino-5-hydroxy-2 c.i.35570 1-Naphthol-8-amino-3,6-disulfonicacid kyselina1-amino-8-naftol-3,6-disulfonova 1-AMINO-8-NAPHTHOL-3,6-DISULFONIC ACID 4-AMINO-5-HYDROXY-2,7-NAPTHALENEDISULFONIC ACID 4-AMINO-5-HYDROXY-2,7-NAPHTHALENEDISULFONIC ACID 8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID 1-Amino-8-naphthol-3,6-disulphonicacid kyselina8-amino-1-naftol-3,6-disulfonova kyselinah 4-amino-5-hydroxynaphthalene-2,7-disulphonic acid 4-amino-5-hydroxy-2,7-naphalene disulfonic acid 1-Amino-8-hydroxy-3,6-disulfonaphthalene 1-Amino-8-hydroxynaphthalene-3,6-disulfonic acid 1-AMINO-8-HYDROXYNAPHTHALENE-3,6-DISULPHONIC ACID 2,7-NAPHTHALENEDISULFONICACID,4-AMINO-5-HYDROXY 8-Amino-1-hydroxy-3,6-naphthalenedisulfonic acid 4-azanyl-5-hydroxy-naphthalene-2,7-disulfonic acid H Acids 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic H ACID (1-AMINO-8-NAPHTHOL -3 6-DISULFONIC ACID) 1-Amino-8-hydroxynaphthalene-3,6-disulphonicaci 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid ISO 9001:2015 REACH TIANFU-CHEM 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid 90-20-0 90-20-0 1300-51-1 C10H9NO7S2 Intermediates of Dyes and Pigments OLED materials,pharm chemical,electronic