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(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one

(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one Structure
(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one structure
CAS No.
510-42-9
Chemical Name:
(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one
Synonyms
Isosinomenine;(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one;Morphinan-7-one, 5,6-didehydro-4-hydroxy-3,6-dimethoxy-17-methyl-, (9α,13α,14α)-
CBNumber:
CB92187676
Molecular Formula:
C19H23NO4
Molecular Weight:
329.39
MDL Number:
MOL File:
510-42-9.mol
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(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one Properties

Melting point 212°C

(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one Chemical Properties,Uses,Production

Description

This alkaloid from Sinomenium acutum forms colourless crystals from Et2 ° and has [α]D + 73° (c 1.2, EtOH). The ultraviolet spectrum exhibits three absorption maxima at 208, 238 and 265 mJ.1.

References

Goto., Froc. Imp. Acad. Tokyo., 2, 7, 167, 414 (1926)

(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one Preparation Products And Raw materials

Raw materials

Preparation Products

(9α,13α,14α)-5,6-Didehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one Isosinomenine Morphinan-7-one, 5,6-didehydro-4-hydroxy-3,6-dimethoxy-17-methyl-, (9α,13α,14α)- 510-42-9