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Methyl 4-oxobutanoate

CAS No.
13865-19-5
Chemical Name:
Methyl 4-oxobutanoate
Synonyms
Methyl 3-Formylpropionate;Einecs 237-611-9;methyl 4-oxobutyrate;METHYL 4-OXOBUTANOATE;Beraprost Impurity 47;Beraprost Impurity 36;Methyl 4-oxobutanoate 90%;Methyl 4-oxobutanoate (~85%);4-Oxobutyric acid methyl ester;4-OXOBUTANOIC ACID METHYL ESTER
CBNumber:
CB9383373
Molecular Formula:
C5H8O3
Molecular Weight:
116.12
MDL Number:
MFCD00082185
MOL File:
13865-19-5.mol
Last updated:2023-12-04 08:57:40

Methyl 4-oxobutanoate Properties

Boiling point 187-188 °C(lit.)
Density 1.109 g/mL at 25 °C(lit.)
refractive index n20/D 1.424(lit.)
Flash point 187 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Colourless
InChIKey DLZVZNAPRCRXEG-UHFFFAOYSA-N
LogP 0.110 (est)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  NA 1993 / PGIII
WGK Germany  3
HS Code  2918300090

Methyl 4-oxobutanoate price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 589098 Methyl 4-oxobutanoate 90% 13865-19-5 1g $510 2024-03-01 Buy
Sigma-Aldrich 589098 Methyl 4-oxobutanoate 90% 13865-19-5 10g $1278 2024-03-01 Buy
TRC M326933 Methyl4-oxobutanoate(~85%) 13865-19-5 50mg $45 2021-12-16 Buy
Matrix Scientific 129829 4-Oxo-butyricacidmethylester 90%+ 13865-19-5 500mg $288 2021-12-16 Buy
Matrix Scientific 129829 4-Oxo-butyricacidmethylester 90%+ 13865-19-5 5g $1512 2021-12-16 Buy
Product number Packaging Price Buy
589098 1g $510 Buy
589098 10g $1278 Buy
M326933 50mg $45 Buy
129829 500mg $288 Buy
129829 5g $1512 Buy

Methyl 4-oxobutanoate Chemical Properties,Uses,Production

Description

Methyl-4-oxobutyrate is a kind of oxobutyrate derivative. It is an important industrial intermediate. It, together with its methanol addition products such as methyl 4,4-dimethoxybutyrate and gamma- methoxy-gamma-butyrolactone are useful intermediates during the preparation of some important industrial compounds such as gamma- butyrolactone, 1,4-butanediol and glutamate. It is also useful as a model substrate during exploring the asymmetric henry reaction since it can assemble a stereodefined lactam with high efficiency and enantiomeric purity.

Uses

Methyl 4-oxobutanoate may be used as a starting material to synthesize (-)-deoxoprosophylline, a piperidine alkaloid with therapeutic potential.

References

Gresham, William F, R. E. Brooks, and W. M. Bruner. "Preparation of methyl 4-oxobutyrate." US2549454. 1951.
Murib, Jawad H, and W. D. Baugh. "Process for the preparation of methyl 4-oxobutyrate and its methanol addition products." US, US5072005. 1991.
https://www.scbt.com/scbt/product/methyl-4-oxobutanoate-13865-19-5

35901-76-9
13865-19-5
Synthesis of Methyl 4-oxobutanoate from 5-Methyl-4-hexenoic acid methyl ester
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Related articles

View Lastest Price from Methyl 4-oxobutanoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl-4-oxobutanoate pictures 2022-09-08 Methyl-4-oxobutanoate
13865-19-5
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Methyl 4-oxobutanoate pictures 2019-12-31 Methyl 4-oxobutanoate
13865-19-5
US $1.00 / KG 1KG 95-99% 1ton Career Henan Chemical Co

Methyl 4-oxobutanoate Spectrum

4-OXOBUTANOIC ACID METHYL ESTER methyl 4-oxobutyrate Succinaldehydic acid, methyl ester Methyl 4-oxobutanoate 90% METHYL 4-OXOBUTANOATE 3-Formylpropanoic acid methyl ester 4-Oxobutyric acid methyl ester Einecs 237-611-9 Butanoic acid, 4-oxo-, Methyl ester Methyl 4-oxobutanoate(Methyl 3-ForMylpropionate) 3-Formylpropionic acid methyl ester Methyl 4-oxobutanoate (~85%) Methyl 3-Formylpropionate (2S)-2-amino-3-(4-prop-8-enoxyphenyl)propanoicacid Beraprost Impurity 47 Beraprost Impurity 36 13865-19-5 H3COCOCH2H2CHO Organic Building Blocks Carbonyl Compounds C1 to C6 Building Blocks Aldehydes Aldehydes C1 to C6 Carbonyl Compounds