| 545-26-6 Basic information More.. |
Product Name: | GITOXIGENIN | Synonyms: | 16β-Hydroxydigitoxigenin, 3β,14,16β-Trihydroxy-5β,20(22)-cardenolide, 5β,20(22)-Cardenolide-3β,14,16β-triol, 3β,14,16β,21-Tetrahydroxy-20(22)-norcholenic acid lactone;3β,14,16β-Trihydroxy-5β,14β-card-20(22)-enolide;Gitoxigenin,98%;3β,14,16β,21-Tetrahydroxy-20(22)-norcholenic acid lactone;3β,14,16β-Trihydroxy-5β,20(22)-cardenolide;5β,20(22)-Cardenolide-3β,14,16β-triol;3,14,16-trihydroxy-,(3-beta,5-beta,16-beta)-card-20(22)-enolid;3-beta,14,16-beta-trihydroxy-5-beta-card-20(22)-enolid | CAS: | 545-26-6 | MF: | C23H34O5 | MW: | 390.51 | EINECS: | 208-886-2 | Mol File: | 545-26-6.mol | |
Use
Recrystallisation of gitoxigenin from aqueous EtOH produces plates of the sesquihydrate which dehydrate on drying at 100o in vacuo. It also recrystallises from Me2CO/MeOH and from EtOAc (the crystals contain 1 mol of EtOAc) with [] D +24.8o (c 1, dioxane). It has UV with max at 310, 485 and 520nm in 96% H2SO4. On heating with ethanolic HCl it yields digitaligenin with loss of H2O. [Smith J Chem Soc 23 1931, Beilstein 8 IV 2456.]
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545-26-6
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