INCANINE

INCANINE Basic information
Product Name:INCANINE
Synonyms:INCANINE;2H-[1,6]Dioxacycloundecino[2,3,4-gh]pyrrolizine-2,6(3H)-dione, 4,5,8,10,12,13,13a,13b-octahydro-5-hydroxy-4,5-dimethyl-3-(1-methylethyl)-, (3R,4S,5R,13aR,13bR)- (9CI)
CAS:480-77-3
MF:C18H27NO5
MW:337.41
EINECS:
Product Categories:
Mol File:480-77-3.mol
INCANINE Structure
INCANINE Chemical Properties
Melting point 96-7°C
Safety Information
RIDADR 1544
HazardClass 6.1(b)
PackingGroup III
MSDS Information
INCANINE Usage And Synthesis
DescriptionThis alkaloid, and its N-oxide (q.v.), have been isolated from Heliotropium olgae Bge., and Trichodesma incanum (Bge.) D.C. The base forms colourless crystals from Me2CO and has a specific rotation of [α]D 38.76° (c 1.625, EtOH). It forms a number of crystalline salts and derivatives, e.g. the hydrochloride, m.p. 199°C; hydrobromide, m.p. 206-8°C; hydriodide, m.p. 206-7°C; nitrate, m.p. 182°C; aurichloride, m.p. 154°C; picrate, m.p. 246°C and the methiodide, m.p. 227-8°C.
ReferencesYunusov, Plekhanova, Dokl. Akad. Nauk. Uzbek SSR, 4, 28 (1953)
Yunusov, P1ekhanova, ibid, 4,31 (1957)
Yunusov, Plekhanova, ibid, 5,13 (1957)
Yunusov, Plekhanova, ibid, 6,19 (1957)
Yunusov, Plekhanova,J. Gen. Chem. USSR, 29, 677 (1959)
Rashkes, Abdullaev, Yunusov, Khim. Prir. Soedin., 10,40 (1974)
INCANINE Preparation Products And Raw materials
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