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Product Name:trilobine
CAS:6138-73-4
Purity:98% Package:5mg;10mg;20mg;50mg;100mg;500mg;1g;1kg
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| Products Intro: |
Product Name:trilobine
CAS:6138-73-4
Purity:98% Package:5mg;25mg;100mg;1g;5g
|
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| | trilobine Basic information |
| Product Name: | trilobine | | Synonyms: | trilobine;(1'α)-6',7-Epoxy-6,12'-dimethoxy-2'-methyloxyacanthan;(1'β)-6',7-Oxy-6,12'-dimethoxy-2'-methyloxyacanthan;2H-22,26-Epoxy-1,24:12,15-dietheno-6,10-metheno-16H-pyrido[2',3':17,18][1,10]dioxacycloeicosino[2,3,4-ij]isoquinoline, 3,4,4a,5,16a,17,18,19-octahydro-9,21-dimethoxy-4-methyl-, (4aS,16aS)- | | CAS: | 6138-73-4 | | MF: | C35H34N2O5 | | MW: | 562.67 | | EINECS: | | | Product Categories: | | | Mol File: | 6138-73-4.mol |  |
| | trilobine Chemical Properties |
| Melting point | 237° | | alpha | D +307° (chloroform) | | density | 1.242±0.06 g/cm3(Predicted) | | pka | 7.85±0.20(Predicted) |
| | trilobine Usage And Synthesis |
| Description | A bisbenzylisoquinoline alkaloid, this base has been isolated from Cocculus
sarmentosus Diels and C. trilobus DC. It crystallizes as colourless prisms and is
dextrorotatory with [α]29D + 296.3° (CHCI3). Both the hydrochloride and hydro_x0002_bromide are crystalline and sparingly soluble in H20 and the dimethiodide has
m.p. 273°C (dec.). Two methoxyl groups and two methylimino groups are
present. With dimethyl sulphate in NaOH, the base yields trilobinemethylmethine
as long, colourless prisms, m.p. 106° C which is optically inactive and on ozonization furnishes 2-methoxy-5:4'-dialdehydodiphenyl ether, m.p. 72-5°C and a
complex dialdehyde, m.p. 124°C. | | Definition | ChEBI: Trilobine is a member of isoquinolines. | | References | Kondo, Tomita., J. Pharm. Soc., Japan, 47, 39 (1927)
Kondo, Tomita., ibid, 48, 83 (1928)
Kondo, Tomita., ibid, SO, 91 (1930)
Faltis., Annalen, 497,69 (1932)
Kondo, Tomita., Arch. Pharm., 274, 65 (1936)
Faltis et al., Ber., 74,79 (1941) |
| | trilobine Preparation Products And Raw materials |
| Raw materials | 2H-1,24:12,15-Dietheno-6,10-metheno-16H-pyrido[2',3':17,18][1,10]dioxacycloeicosino[2,3,4-ij]isoquinoline, 17-benzoyl-3,5,16a,17,18,19-hexahydro-9,21,22,26-tetramethoxy-, (S)- (9CI) |
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