7-hydroxynaphthalene-2-sulphonic acid

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Products Intro: Product Name:7-hydroxynaphthalene-2-sulphonic acid
CAS:92-40-0
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Products Intro: Product Name:2-Hydroxynaphthlene-7-sulfonic acid
CAS:92-40-0
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CAS:92-40-0
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Products Intro: Product Name:2-Hydroxynaphthlene-7-sulfonic acid
CAS:92-40-0
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Products Intro: Product Name:(4Z)-4-(phenylmethylene)oxolane-2,3-dione
CAS:92-40-0
Purity:0.97 Package:mgs,gs,kgs Remarks:A844223
7-hydroxynaphthalene-2-sulphonic acid Basic information
Product Name:7-hydroxynaphthalene-2-sulphonic acid
Synonyms:7-hydroxynaphthalene-2-sulphonic acid;2-Naphthol-7-sulfonic acid;2-Hydroxynaphthalene-7-sulfonicacid;2-Hydroxy-7-naphthalenesulfonic acid;7-Hydroxynaphthalene-2-sulfonic acid;2-Naphthalenesulfonic acid, 7-hydroxy-;(4Z)-4-(phenylmethylene)oxolane-2,3-dione;2-Hydroxynaphthlene-7-sulfonic acid
CAS:92-40-0
MF:C10H8O4S
MW:224.23
EINECS:202-153-0
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Mol File:92-40-0.mol
7-hydroxynaphthalene-2-sulphonic acid Structure
7-hydroxynaphthalene-2-sulphonic acid Chemical Properties
density 1.549±0.06 g/cm3(Predicted)
pka0.21±0.40(Predicted)
EPA Substance Registry System2-Naphthalenesulfonic acid, 7-hydroxy- (92-40-0)
Safety Information
RIDADR 1759
HazardClass 8
PackingGroup III
MSDS Information
7-hydroxynaphthalene-2-sulphonic acid Usage And Synthesis
Chemical Properties2-Hydroxynaphthalene-7-sulfonic acid [92- 40-0]. (7-hydroxynaphthalene-2-sulfonic acid), F acid, Cassella acid, C10H8O4S, Mr 224.23, is soluble in water, from which it can be recrystallized as the monohydrate (mp 89℃). The sodium and potassium salts are also readily soluble, but the barium salt is sparingly soluble. Iron(III) chloride gives a dark blue color with neutral solutions of 2-Hydroxynaphthalene-7-sulfonic acid. Azo coupling and nitrosation occurs in the 1-position. Sulfonation gives a variety of products depending on the conditions.
Uses2-Hydroxynaphthalene-7-sulfonic acid is used as an intermediate in the production of 2-aminonaphthalene-7-sulfonic acid, 2-hydroxynaphthalene-3,7-disulfonic acid, and 2,7-dihydroxynaphthalene. It has minor uses as an azo coupling component.
PreparationNaphthalene-2,7-disulfonic acid is heated with aqueous sodium hydroxide under pressure at 230℃ for 5 h and then at 260℃ for another 5 h. After neutralizing and screening, the liquor is acidified to precipitate the product, which is isolated after boiling off the sulfur dioxide and cooling to 30℃.
7-hydroxynaphthalene-2-sulphonic acid Preparation Products And Raw materials
Preparation Products2-Naphthalenesulfonic acid, 8-amino-5-[[4-[(2-hydroxy-7-sulfo-1-naphthalenyl)azo]-5-methoxy-2-methylphenyl]azo]-, disodium salt-->Direct Blue 157
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