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| | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one Basic information |
| Product Name: | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one | | Synonyms: | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one;Sauroxine;1H-5,10b-Propano-1,7-phenanthrolin-8(7H)-one, 2,3,4,4a,5,6,9,10-octahydro-1,12-dimethyl-, (4aS,5S,10bR,12R)- | | CAS: | 3279-74-1 | | MF: | C17H26N2O | | MW: | 274.4 | | EINECS: | | | Product Categories: | | | Mol File: | 3279-74-1.mol |  |
| | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one Chemical Properties |
| | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one Usage And Synthesis |
| Description | One of the numerous alkaloids obtained from the Lycopodium species, this base occurs in L. sausaurus and gives colourless crystals from Me2CO. It is laevorotatory having [α]20D
- 71.8° (c 0.792, EtOH). The ultraviolet spectrum consists
of a single absorption maximum at 257 mJ.l.. The alkaloid may be characterized as
the methiodide which forms colourless needles from aqueous Me2CO, m.p.
258°C. When heated with Pd-C in a stream of nitrogen at 290-300°C it yields
7-methylquinoline and 6-methyl-a-pyridone. From the above structure it will be
seen that the alkaloid is a stereoisomer of a-Obscurine (q.v.). | | Definition | ChEBI: Sauroxine is a sesquiterpenoid. | | References | Deulofeu, DeLanghe.,J. A mer. Chern. Soc., 64, 968 (1942)
Structure:
Ayer et aZ., Tetrahedron, 21,2168 (1965) |
| | (12α)-3,18-Dihydro-17-methyllycodin-1(2H)-one Preparation Products And Raw materials |
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