ChemicalBook >>3-Fluoroaniline>>1-Amino-3-fluorobenzene(372-19-0)

1-Amino-3-fluorobenzene(372-19-0)

1-Amino-3-fluorobenzene(372-19-0)
Product IdentificationBack to Contents
【Product Name】

1-Amino-3-fluorobenzene
【Synonyms】

3-Fluoroaniline
Benzenamine, 3-fluoro-
【CAS】

372-19-0
【Formula】

C6H6FN
【Molecular Weight】

111.12
【EINECS】

206-747-0
【RTECS】

BY1400000
【RTECS Class】

Other
【Beilstein/Gmelin】

1305471
【Beilstein Reference】

4-12-00-01101
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Brown liquid/
【Solubility in water】

Slightly soluble
【Melting Point】

-2
【Boiling Point】

186
【Density】

1.16 g/cm3 (16 C)
【pKa/pKb】

3.5(at 25℃) (pKa)
【Vapor Density】

3.83
【Refractive Index】

1.5414 (15.8 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Aspiration may lead to pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
【Skin】

Causes skin irritation. May cause cyanosis of the extremities.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Effects may be delayed 2 to 4 hours. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 20/21/22 36/38
【EC Safety Phrase】

S 26 36/37/39
【UN (DOT)】

2941
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged or repeated skin contact may cause dermatitis.
Fire Fighting MeasuresBack to Contents
【Flash Point】

77
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

9
【Incompatibilities】

Acids, acid anhydrides, acid chlorides, chloroformates.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2941
【Hazard Class】

6.1
【Packing Group】

III
【HS Code】

2921 42 10
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