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Acenaphthenequinone(82-86-0)

Acenaphthenequinone(82-86-0)
Product IdentificationBack to Contents
【Product Name】

Acenaphthenequinone
【Synonyms】

1,2-Acenaphthenedione
1,2-Acenaphthenequinone
2,4-Dioxy-3,3-diethyl-5-methylpiperidine
3,3-Diethyl-2,4-dioxo-5-methylpiperidine
3,3-Diethyl-5-methyl-2,4-piperidinedione
3,3-Diethyl-5-methylpiperidine-2,4-dione
Acenaphthaquinone
Acenaphthoquinone
Methyprylon
【CAS】

82-86-0
【CAS】

125-64-4
【Formula】

C10H17NO2
【Formula】

C12H6O2
【Molecular Weight】

182.18
【Molecular Weight】

183.25
【EINECS】

201-441-3
【EINECS】

204-745-4
【RTECS】

AB1024500
【RTECS】

TM7350000
【RTECS Class】

Drug
【RTECS Class】

Drug; Human Data
【Merck】

12,6216
【Beilstein/Gmelin】

879172
【Beilstein/Gmelin】

82860
【Beilstein Reference】

4-07-00-02498
【Beilstein Reference】

5-21-09-00615
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Yellow needles from acetic acid.
【Solubility in water】

Soluble
【Solubility in water】

Insoluble
【Melting Point】

252 - 255
【Melting Point】

84
【Boiling Point】

351
【Density】

1.4800 g/cm3 (20C)
【pKa/pKb】

12.11 (pKa)
【Partition Coefficient】

1.74
【Usage】

Fungicide.
【Usage】

Medication.
【Refractive Index】

1.4683 (71 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
【Inhalation】

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Inhalation】

If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
【Skin】

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
【Handling】

Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Hazards IdentificationBack to Contents
【Ingestion】

Ausea, vomiting and diarrhea are common side effects.
【Inhalation】

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
【Skin】

Causes skin irritation.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【EC Risk Phrase】

R 36/37/38
【EC Safety Phrase】

S 26 36
【UN (DOT)】

1325
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Respirators】

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
【Fire Potential】

Flammable/combustible material. May be ignited by friction, heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Stability】

No data.
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】

Strong oxidizing agents.
【Disposal Code】

3
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1325
【Hazard Class】

4.1
【Packing Group】

II; III
【HS Code】

2914 69 90
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