ChemicalBook >>3-Bromotoluene>>1-Bromo-3-methylbenzene(591-17-3)

1-Bromo-3-methylbenzene(591-17-3)

1-Bromo-3-methylbenzene(591-17-3)
Product IdentificationBack to Contents
【Product Name】

1-Bromo-3-methylbenzene
【Synonyms】

1-Bromo-3-methylbenzene
3-Bromo-1-methylbenzene
3-Methyl-1-Bromobenzene
3-Methylbromobenzene
m-Bromotoluene
m-Methylbromobenzene
【CAS】

591-17-3
【Formula】

C7H7Br
【Molecular Weight】

171.04
【EINECS】

209-702-3
【RTECS】

XS7965400
【RTECS Class】

Other
【Merck】

13,1424
【Beilstein/Gmelin】

1903633
【Beilstein Reference】

4-05-00-00827
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear colorless liquid.
【Solubility in water】

51.3 mg/L
【Melting Point】

-40
【Boiling Point】

183.7
【Vapor Pressure】

1.1 (25 C)
【Density】

1.41 g/cm3 (20 C)
【Partition Coefficient】

3.41
【Heat Of Vaporization】

40.1 kJ/mol
【Usage】

Research chemical.
【Vapor Density】

5.9
【Refractive Index】

1.551 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】

Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause cardiac abnormalities. Inhalation at high concentrations may cause CNS depression and asphixiation. May cause burning sensation in the chest.
【Skin】

Causes skin irritation. May cause cyanosis of the extremities.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause cardiac disturbances. May cause central nervous system depression. Ingestion of large amounts may cause CNS depression.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 22 36/37/38
【EC Safety Phrase】

S 26 36/37/39
【UN (DOT)】

1993
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

60
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution. Runoff to sewer may create fire or explosion hazard. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use water spray, fog or regular foam.
【Fire Potential】

This chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Disposal Code】

2
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1993
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2903 69 90
Company Name: SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel: 021-69106960 13701823733
Fax: 021-69106780
WebSite: www.bangchengchem.com/
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel: 021-61259108 18621169109
Fax: 86-21-61259102
WebSite: www.meryer.com/cn/index/
Company Name: Alfa Aesar
Tel: 400-6106006
Fax: 021-67582001/03/05
WebSite: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.
Tel: 021-67121386
Fax: 021-67121385
WebSite: https://www.tcichemicals.com/CN/zh/
Company Name: Beijing dtftchem Technology Co., Ltd.
Tel: 010-60275820 13031183356
Fax: 010-60270825
WebSite: www.dtfchem.com
Company Name: Energy Chemical
Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
WebSite: http://www.energy-chemical.com
Company Name: Wuhan Chemwish Technology Co., Ltd
Tel: 86-027-67849912
Fax: 86-027-87531808
WebSite: www.chemwish.com
Company Name: Capot Chemical Co., Ltd
Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
WebSite: www.capotchem.com