BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE synthesis
- Product Name:BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
- CAS Number:79269-71-9
- Molecular formula:C18H18Cl2Ti
- Molecular Weight:353.11
35059-40-6
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Yield: 90%
Reaction Conditions:
with sodium in tetrahydrofuran;benzenebyproducts: NaCl; to metallic Na in THF t-BuC5H5 added at -20°C; after 2 h n-BuCl in THF added dropwise; stirred for 10 h; NaCl filtered off; TiCl4 in THF/benzene added at 0°C to the filtrate; stirred for 3 h at -20°C; satd. with dry HCl; solvent evapd. in vacuo; residue extd. (HCl-satd. CHCl3); recrystd. (CHCl3); elem. anal.;
References:
Strelets, V. V.;Soloveichik, G. L.;Sizov, A. I.;Bulichev, B. M.;Rusina, A.;Vlchek, A. A. [Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1983,vol. 32,p. 2241 - 2245][Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1983,p. 2493 - 2497]