ChemicalBook CAS DataBase List Diisopropylamine

Diisopropylamine synthesis

13synthesis methods

Product Name:Diisopropylamine
CAS Number:108-18-9
Molecular formula:C6H15N
Molecular Weight:101.19

Synthesis of diisopropylamine: using acetone, ammonia and hydrogen as raw materials, and reacting at 150-220 ° C under normal pressure with nickel, copper and clay as catalysts, the conversion rate of acetone is 98%, and the crude products of mono- and diisopropylamine are obtained, After rectification, Isopropylamine and diisopropylamine were obtained.

67-63-0 Synthesis

67-63-0
1548 suppliers
$17.00/25ML

75-31-0 Synthesis

75-31-0
412 suppliers
$14.00/25mL

108-18-9
353 suppliers
$10.00/1g

67-64-1
6 suppliers
$19.10/10ml

Yield:75-31-0 59.9%

Reaction Conditions:

with ammonia;hydrogen at 160; under 760.051 Torr; for 0.5 h;Catalytic behavior;Flow reactor;Inert atmosphere;Reagent/catalyst;

Steps:

2.4 Catalytic Activity Tests

General procedure: All catalytic experiments were performed under atmosphericpressure at continuous-flow in a fixed bedmicroreactor. Prior to testing, the catalysts were activatedat 600 °C for 3 h under a flow of purified H2 (50 cm³min^-1) and kept at the desired temperature to establish astandard operating procedure, allowing time for productdistribution to stabilize. Standard conditions involved thefollowing reaction parameters: T = 160 °C; weight hourlyspace velocity (WHSV, h^-1) = 4.3; and feed composition(IPA/NH3/H2/N2; molar ratio) = 1/4/6/22.8. The partialpressure of IPA was fixed at 3 kPa. For the comparison of selectivities of MIPA over variousNi/Al2O3 catalysts, space velocity was controlled in therange 2.3-19.1 at 150 °C. To maintain constant partialpressures of the reactants, nitrogen was used as a diluent.The reaction products were analyzed on-line using aChrompack-CP-9001 gas chromatograph equipped with aCP-Volamine capillary column (60 mm x 0.32 mm) and aflame ionization detector. The conversion of IPA, selectivityand WHSV were defined as follows: where FIPA and Fi are molar flow rates of IPA and i productswhich are MIPA, diisopropylamine (DIPA), acetone,respectively. MWIPA is a molecular weight of IPA. Ci is acarbon number of i products.

References:

Cho, Jun Hee;An, Sang Hee;Chang, Tae-Sun;Shin, Chae-Ho [Catalysis Letters,2016,vol. 146,# 4,p. 811 - 819]

75-31-0 Synthesis

75-31-0
412 suppliers
$14.00/25mL

67-64-1
6 suppliers
$19.10/10ml

108-18-9
353 suppliers
$10.00/1g

References

67-63-0 Synthesis

67-63-0
1548 suppliers
$17.00/25ML

75-31-0 Synthesis

75-31-0
412 suppliers
$14.00/25mL

108-18-9
353 suppliers
$10.00/1g