ChemicalBook CAS DataBase List Nitrosobenzene

Nitrosobenzene synthesis

13synthesis methods

Product Name:Nitrosobenzene
CAS Number:586-96-9
Molecular formula:C6H5NO
Molecular Weight:107.11

62-53-3 Synthesis

62-53-3
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586-96-9
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$20.00/1G

Yield:586-96-9 90%

Reaction Conditions:

with urea hydrogen peroxide adduct;carbonic acid dimethyl ester at 20; for 2 h;Catalytic behavior;Reagent/catalyst;Temperature;

Steps:

General procedure for amine oxidation to nitrosoarene
General procedure: To a solution of 1 mmol amine in 2 mL DMC, was added3 mmol UHP and 0.03 g catalyst. The mixture was stirredat room temperature for 2 h. Then the catalyst was removedusing magnetic decantation. The reaction vessel was washedwith water and extracted with dichloromethane (3 × 10 mL).The organic layer was dried with Na2SO4and the solventwas evaporated under vacuum. The crude product was purifiedusing column chromatography if needed.

References:

Jadidi Nejad, Masoume;Yazdani, Elahe;Kazemi Miraki, Maryam;Heydari, Akbar [Chemical Papers,2019,vol. 73,# 7,p. 1575 - 1583]

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