ChemicalBook--->CAS DataBase List--->102-92-1

102-92-1

102-92-1 Structure

102-92-1 Structure
IdentificationMore
[Name]

Cinnamoyl chloride
[CAS]

102-92-1
[Synonyms]

2-PROPENOYL CHLORIDE, 3-PHENYL-
3-PHENYL-2-PROPENOYL CHLORIDE
3-PHENYLACRYLYL CHLORIDE
3-PHENYLPROPENOYL CHLORIDE
AKOS BBS-00003908
CINNAMIC ACID CHLORIDE
CINNAMOYL CHLORIDE
TRANS-3-PHENYLACRYLOYL CHLORIDE
TRANS-3-PHENYLACRYLOYL PROPENOYL CHLORIDE
TRANS-CINNAMOYL CHLORIDE
(2E)-3-Phenyl-2-propenoyl chloride
3-phenyl-2-propenoylchlorid
3-phenyl-acryloylchloride
beta-Phenylacryloyl chloride
Cinnamic chloride
Phenylacrylchloride
Phenylacrylyl chloride
CINNAMOYL CHLORIDE PREDOMINANTLY TRANS
Cinnamoyl chloride, 98%, predominantly trans
CINNAMOYL CHLOCIDE
[EINECS(EC#)]

203-065-5
[Molecular Formula]

C9H7ClO
[MDL Number]

MFCD00000732
[Molecular Weight]

166.6
[MOL File]

102-92-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to yellowish crystalline solid
[Melting point ]

35-37 °C (lit.)
[Boiling point ]

256-258 °C (lit.)
[density ]

d445.3 1.1617
[refractive index ]

nD42.5 1.614
[Fp ]

>230 °F
[storage temp. ]

0-6°C
[solubility ]

dioxane: 0.1 g/mL, clear
[form ]

Crystalline Solid
[color ]

White to yellow
[Water Solubility ]

DECOMPOSES
[Merck ]

13,2323
[BRN ]

606265
[CAS DataBase Reference]

102-92-1(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Propenoyl chloride, 3-phenyl-(102-92-1)
[EPA Substance Registry System]

102-92-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29163990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Thionyl chloride-->Carbon dioxide-->Oxalyl chloride-->Sodium cinnamate
[Preparation Products]

Cinnamamide-->Pentyl cinnamate-->3-Phenyl-2-propen-1-ol-->8-BROMOQUINOLIN-2(1H)-ONE-->6-Methyl-4-phenylchroman-2-one-->Oroxylin A-->N,N-DIPHENYLCINNAMAMIDE-->1-cinnamoyl-4-(2-pyridinyl)piperazine-->2-Propenamide, N-(3-aminopropyl)-3-phenyl-, (E)- (9CI)-->N-(3-Hydroxyphenyl)cinnamamide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Phenyl-2-propenoyl chloride(102-92-1).msds
Hazard InformationBack Directory
[Hazard]

Skin irritant.
[Chemical Properties]

white to yellowish crystalline solid
[Uses]

Titrimetric determination of small amounts of water.
[Synthesis Reference(s)]

Organic Syntheses, Coll. Vol. 3, p. 714, 1955
Tetrahedron Letters, 14, p. 5121, 1973 DOI: 10.1016/S0040-4039(01)87403-7
[Purification Methods]

Refractionate it in a vacuum until the distillate solidifies on cooling, and recrystallise it from pet ether. The trans-amide has m 145-150o (from H2O) [Beilstein 9 III 2711]. [Adams & Ulich J Am Chem Soc 42 605 1920, Bergmann et al. J Chem Soc 2524 1952, Beilstein 9 H 587, 9 I 233, 9 II 390, 9 III 2710, 9 IV 2020.]
Spectrum DetailBack Directory
[Spectrum Detail]

Cinnamoyl chloride(102-92-1)1HNMR
Cinnamoyl chloride(102-92-1)Raman
Cinnamoyl chloride(102-92-1)IR
Cinnamoyl chloride(102-92-1)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cinnamoyl chloride, predominantly trans, 98%(102-92-1)
[Sigma Aldrich]

102-92-1(sigmaaldrich)
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