ChemicalBook--->CAS DataBase List--->1306-24-7

1306-24-7

1306-24-7 Structure

1306-24-7 Structure
IdentificationMore
[Name]

CADMIUM SELENIDE
[CAS]

1306-24-7
[Synonyms]

CADMIUM SELENIDE
cadmiumselenide(cdse)
Cadmium selenide Coating quality Balzers
Cadmium selenide,(99.999+%-Cd)
Cadmiumselenidemetalsbasisblackpowder
Lumidot CdSe/ZnS 610
CADMIUM SELENIDE COATING QUALITY BALZER&
CADMIUM SELENIDE, CA. 10 MICRON, 99.99%, ELECTRONIC GRADE
Lumidot(TM) CdSe/ZnS 595
Lumidot# CdSe-6, quantum dot nanoparticles kit, core type
Lumidot CdSe/ZnS 630
99.995%(metalsbasis)
CADMIUM SELENIDE ULTRAPURE, 99.99%
Cadmiumselenide(99.999+%-Cd)PURATREM
cadmium selemide
CADMIUM SELENIDE: (99.999%-CD), METALS BASIS
Cadmium selenide, 99.995% (metals basis)
Cadmium selenide, 99.999% (metals basis)
[EINECS(EC#)]

215-148-3
[Molecular Formula]

CdSe
[MDL Number]

MFCD00010917
[Molecular Weight]

191.37
[MOL File]

1306-24-7.mol
Chemical PropertiesBack Directory
[Melting point ]

>1350°C
[density ]

5.81 g/mL at 25 °C(lit.)
[refractive index ]

2.87 (900 nm)
[storage temp. ]

2-8°C
[solubility ]

insoluble in H2O
[form ]

granular
[color ]

Brown-red to black
[Specific Gravity]

5.81
[Water Solubility ]

Insoluble in water.
[Crystal Structure]

Hexagonal, Wurtzite (Zincite) Structure - Space Group P 63mc
[Sensitive ]

air sensitive, store cold
[Merck ]

14,1626
[Exposure limits]

ACGIH: TWA 0.01 mg/m3; TWA 0.002 mg/m3; TWA 0.2 mg/m3
NIOSH: IDLH 9 mg/m3; IDLH 1 mg/m3; TWA 0.2 mg/m3
[Stability:]

store cold
[CAS DataBase Reference]

1306-24-7(CAS DataBase Reference)
[EPA Substance Registry System]

Cadmium selenide (CdSe) (1306-24-7)
Hazard InformationBack Directory
[Chemical Properties]

3–12mm pieces (sintered), and -325 mesh 10μm or less with 99.999% purity; white to brown; cub or hexagonal crystal(s); hex: a=0.4309nm, c=0.7021 nm, enthalpy of fusion 305.307 kJ/mol; becomes red in sunlight; used as a red pigment, in semiconductors, and as an evaporation material and sputtering target to produce photoconductive films and infrared filters; possible use in the electrofabrication of microdiode arrays [HAW93] [MER06] [CER91] [KLE93] [KRE91]
[Uses]

In photoconductors, semiconductors, photoelectric cells, and rectifiers; in phosphors.
[Physical properties]

The energy gap of the hexagonal CdSe obtained from the absorption measurement Eg (Γ6–Γ1 ) is Eg=1.84 eV, temperature coefficient -4.6×10-4 eV/K, and pressure coefficient 3.7×10-6 eV/kg–cm -2 .
The band structure of cubic CdSe is similar to that of GaAs.
[Application]

Cadmium selenide is used as a photoconductive detector for λ: 0.3–0.72 mm (a sharp peak at 0.7 mm) at room temperature. The typical performances are as follows:
Peak detectivity: 2.1×1011 cm Hz1/2/watt, (λ: 0.7 mm)
Response time: ca. 12 ms
Intermittent frequency: 90 Hz
Dominant noise: current noise
[Definition]

ChEBI: Cadmium selenide is a cadmium molecular entity.
[Production Methods]

A single crystal can be grown artificially through the vapor phase method or the Stockbarger method.
To obtain evaporated films, the source materials are heated in the alumina crucible with a nichrome heater. Crystal with a larger grain size is obtained at a higher substrate temperature.
The following corrosives are reported:
HNO3 (water cleansing after 2–3 s)
H2SO4 (water cleansing after 5–10 s)
18 N solution of 30 HNO3:0.1 HCl:20 H2SO4 (40℃, 8 s, cleansing with concentrated H2SO4)
3 HCl:1 HNO3
[General Description]

CdSe crystal can exist in solid hexagonal or cubic structure. CdSe behaves as an n-type semiconductor, with a bandgap of 1.74 eV (300K).1
[Flammability and Explosibility]

Notclassified
[Structure and conformation]

The space lattice of CdSe (Cadmium selenide) belongs to the two types of crystal system, the cubic system, with the zinc-blend type structure that has a lattice constant of a=0.605 nm, and the hexagonal system, with the wurtzite type structure that has lattice constants of a=0.430 nm and c=0.702 nm.
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R21:Harmful in contact with skin.
R23/25:Toxic by inhalation and if swallowed .
R33:Danger of cumulative effects.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2570 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

EV2300000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

28429090
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

cadmium selenide(1306-24-7).msds
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Cadmium selenide, 99.999% (metals basis)(1306-24-7)
[Sigma Aldrich]

1306-24-7(sigmaaldrich)
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