| Identification | More | [Name]
3-Bromo-2-pyridinamine | [CAS]
13534-99-1 | [Synonyms]
2-AMINO-3-BROMOPYRIDINE
3-BROMO-2-PYRIDINAMINE
3-BROMOPYRIDIN-2-AMINE
3-BROMO-PYRIDIN-2-YLAMINE
IFLAB-BB F1371-0194
TIMTEC-BB SBB005538
2-Pyridinamine, 3-bromo-
2-AMINO-3-BROMOPYRIDINE 97%
3-Bromopyridine-2-amine | [EINECS(EC#)]
629-620-5 | [Molecular Formula]
C5H5BrN2 | [MDL Number]
MFCD03095187 | [Molecular Weight]
173.01 | [MOL File]
13534-99-1.mol |
| Chemical Properties | Back Directory | [Appearance]
grey to brown powder | [Melting point ]
63-67 °C | [Boiling point ]
232.0±20.0 °C(Predicted) | [density ]
1.6065 (rough estimate) | [vapor pressure ]
0.83-1.8Pa at 20-25℃ | [refractive index ]
1.5182 (estimate) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Powder | [pka]
4.14±0.36(Predicted) | [color ]
Gray to brown | [BRN ]
109867 | [LogP]
1.5 at 20℃ and pH7 | [CAS DataBase Reference]
13534-99-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HazardClass ]
IRRITANT | [PackingGroup ]
II | [HS Code ]
29333990 |
| Hazard Information | Back Directory | [Chemical Properties]
grey to brown powder | [Uses]
2-Amino-3-bromopyridine may be used to synthesize:
- 2-acylamido-3-bromopyridines
- 2-anilino-3-bromopyridine
- 3-[(2-methoxyphenyl)ethynyl]pyridin-2-amine
- 3-[(4-methoxyphenyl)ethynyl]pyridin-2-amine
- N-(bromopyridyl)amidines
- carbolines via palladium catalyzed arylation followed by palladium catalyzed amination reaction
- 2-amino-3-cyanopyridine via palladium catalyzed cyanation reaction with potassium ferro-cyanide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene [DBU]
- nitro-substituted N,N′-dipyridinylamines via palladium catalyzed coupling reaction with 2-chloro-3-nitropyridine in the presence of Xantphos ligand
- 2-amino-3-iodopyridine via reaction with sodium iodide in the presence of copper(I)iodide and trans-N,N′-dimethylcyclohexane-1,2-diamine
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