| Identification | Back Directory | [Name]
tBuXPhos Pd G3 | [CAS]
1447963-75-8 | [Synonyms]
tBuXPhos Pd G3
tBuXPhos Pd G3 97%
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
[2'-(Amino)[1,1'-biphenyl]-2-yl][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [t-BuXPhos Palladacycle]
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)- | [Molecular Formula]
C42H58NO3PPdS | [MDL Number]
MFCD22666411 | [MOL File]
1447963-75-8.mol | [Molecular Weight]
794.38 |
| Chemical Properties | Back Directory | [Melting point ]
130-140°C | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [form ]
Powder | [color ]
yellow | [InChIKey]
KKVLHKIBKWORMK-UHFFFAOYSA-N | [SMILES]
P(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C)(C(C)(C)C)C(C)(C)C |
| Hazard Information | Back Directory | [Physical properties]
tBuXPhos-Pd-G3 is in the form of a dark grey crystalline powder. | [Uses]
tBuXPhos Pd G3 may be used to synthesize 4-cyano-7-azaindole from 4-chloro-7-azaindole by cyanation reaction. It may also be used for the α-arylation reaction of acetate esters at room temperature. | [Reactions]
Mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.
 | [General Description]
tBuXPhos Pd G3(1447963-75-8) is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuXPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. | [storage]
tBuXPhos Pd G3 should be stored in an airtight, dry and low temperature. |
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