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19013-37-7

19013-37-7 Structure

19013-37-7 Structure
IdentificationMore
[Name]

DIMETHYL 3-METHYLGLUTARATE
[CAS]

19013-37-7
[Synonyms]

Methyl 3-methylgutarate
DIMETHYL 3-METHYLGLUTARATE
imethyl3-methylpentanedioate
Dimethyl 3-methylglutarate 99%
Dimethyl 3-methylpentanedioate
3-Methylglutaric acid dimethyl
3-Methylpentanedioic acid dimethyl
3-Methylglutaric acid dimethyl ester
Glutaric acid, 3-methyl-, dimethyl ester
3-METHYL-PENTANEDIOIC ACID DIMETHYL ESTER
Pentanedioic acid, 3-methyl-, 1,5-dimethyl ester
[EINECS(EC#)]

200-258-5
[Molecular Formula]

C8H14O4
[MDL Number]

MFCD00075608
[Molecular Weight]

174.19
[MOL File]

19013-37-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

110 °C/19 mmHg (lit.)
[density ]

1.052 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.425(lit.)
[Fp ]

207 °F
[CAS DataBase Reference]

19013-37-7(CAS DataBase Reference)
Safety DataBack Directory
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Dimethyl 3-methylglutarate may be used in the synthesis of (R)- and (S)-4-amino-3-methylbutanoic acids, via initial enantioselective hydrolysis with pig liver esterase. It may be used in the preparation of optically active form of verrucarinic acid derivative. It may be used as building block for chemoenzymatic asymmetric synthesis.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 59, p. 2132, 1994 DOI: 10.1021/jo00087a033
Tetrahedron Letters, 26, p. 5643, 1985 DOI: 10.1016/S0040-4039(01)80908-4
[General Description]

Dimethyl 3-methylglutarate is an ester. It participates in the synthesis of (R,Z)- muscenone, a valuable perfume ingredient.
Spectrum DetailBack Directory
[Spectrum Detail]

DIMETHYL 3-METHYLGLUTARATE(19013-37-7)1HNMR
DIMETHYL 3-METHYLGLUTARATE(19013-37-7)Raman
DIMETHYL 3-METHYLGLUTARATE(19013-37-7)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

19013-37-7(sigmaaldrich)
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