ChemicalBook--->CAS DataBase List--->33524-31-1

33524-31-1

33524-31-1 Structure

33524-31-1 Structure
IdentificationMore
[Name]

2,5-DIMETHOXYBENZYL ALCOHOL
[CAS]

33524-31-1
[Synonyms]

2,5-DIMETHOXYBENZYL ALCOHOL
AURORA KA-7072
RARECHEM AL BD 0533
(2,5-Dimethoxyphenyl)methanol
Benzenemethanol, 2,5-dimethoxy-
2,5-DIMETHOXYBENZYL ALCOHOL 99%
2,5-Dimethoxy-1-(hydroxymethyl)benzene
2,5-Dimethoxybenzenemethanol
[EINECS(EC#)]

251-562-0
[Molecular Formula]

C9H12O3
[MDL Number]

MFCD00004615
[Molecular Weight]

168.19
[MOL File]

33524-31-1.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to light yellow viscous liquid
[Melting point ]

45-48 °C
[Boiling point ]

122-125 °C1 mm Hg(lit.)
[density ]

1.173 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.547(lit.)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform, Methanol
[form ]

Viscous Liquid
[pka]

14.16±0.10(Predicted)
[color ]

Clear colorless to light yellow
[BRN ]

1947607
[LogP]

1.019 (est)
[CAS DataBase Reference]

33524-31-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S36/37:Wear suitable protective clothing and gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[HS Code ]

29094980
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzenemethanol, 2,5-dimethoxy-, 1-acetate-->2,5-dihydroxybenzyl alcohol-->2,5-Dimethoxybenzylbromide-->2,5-Dimethoxybenzaldehyde-->1,4-Dimethoxybenzene
[Preparation Products]

2,5-Dimethoxybenzylamine
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to light yellow viscous liquid
[Uses]

2,5-Dimethoxybenzyl alcohol was used as starting reagent in the synthesis of [(S)S]-3,6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde. It was used in the synthesis of daunornycinone. It was also used in the preparation of pillar[n]arenes (n = 5 or 6) via cyclooligomerization reaction with an appropriate Lewis acid catalyst.
[Uses]

2,5-Dimethoxybenzyl Alcohol can be used as a self-indicating standard for the determination of organolithium reagents
[Synthesis Reference(s)]

Tetrahedron Letters, 35, p. 6207, 1994 DOI: 10.1016/S0040-4039(00)73392-2
Spectrum DetailBack Directory
[Spectrum Detail]

2,5-DIMETHOXYBENZYL ALCOHOL(33524-31-1)MS
2,5-DIMETHOXYBENZYL ALCOHOL(33524-31-1)1HNMR
2,5-DIMETHOXYBENZYL ALCOHOL(33524-31-1)13CNMR
2,5-DIMETHOXYBENZYL ALCOHOL(33524-31-1)IR1
2,5-DIMETHOXYBENZYL ALCOHOL(33524-31-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,5-Dimethoxybenzyl alcohol, 99%(33524-31-1)
[Sigma Aldrich]

33524-31-1(sigmaaldrich)
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