ChemicalBook--->CAS DataBase List--->3680-02-2

3680-02-2

3680-02-2 Structure

3680-02-2 Structure
IdentificationMore
[Name]

Methyl vinyl sulfone
[CAS]

3680-02-2
[Synonyms]

METHYL VINYL SULFONE
METHYL VINYL SULPHONE
VINYL METHYL SULFONE
(methylsulfonyl)-ethen
1-(Methylsulfonyl)ethylene
Sulfone, methyl vinyl
sulfone,methylvinyl
URI 718
(methylsulphonyl)ethylene
Methylvinylsulfone,98%,stab.with200ppm4-t-butylphenol
Methyl vinyl sulfone, stabilized, 98%
Ethene, (methylsulfonyl)-
METHYL VINYL SULFONE , STABILIZED WITH 200PPM 4-T-BUTYLPHENOL
METHYL VINYL SULFONE, 98%, STABILIZED
Ethenyl methyl sulfone
Methyl ethenyl sulfone
Methyl vinyl sulfone, 98%, stab. with 200ppm 4-tert-butylphenol
[EINECS(EC#)]

222-958-0
[Molecular Formula]

C3H6O2S
[MDL Number]

MFCD00007567
[Molecular Weight]

106.14
[MOL File]

3680-02-2.mol
Chemical PropertiesBack Directory
[Appearance]

light yellow liquid
[Boiling point ]

115-117 °C19 mm Hg(lit.)
[density ]

1.212 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.463(lit.)
[Fp ]

>230 °F
[storage temp. ]

0-6°C
[form ]

Liquid
[color ]

Clear colorless to slightly yellow
[Specific Gravity]

1.212
[Stability:]

Stable. Incompatible with strong oxidizing agents. Irritant.
[BRN ]

878198
[CAS DataBase Reference]

3680-02-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethene, (methylsulfonyl)-(3680-02-2)
[EPA Substance Registry System]

3680-02-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T+,T,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R27:Very Toxic in contact with skin.
R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2810 6.1/PG 1
[WGK Germany ]

3
[RTECS ]

WR6825000
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29309099
Hazard InformationBack Directory
[General Description]

Clear pale yellow liquid.
[Reactivity Profile]

METHYL VINYL SULFONE(3680-02-2) is incompatible with oxidizing agents . Can react exothermically with reducing agents to release hydrogen gas or hydrogen sulfide. In the presence of various catalysts (such as acids) or initiatiators, can undergo exothermic polymerization reactions.
[Air & Water Reactions]

Water soluble.
[Fire Hazard]

This chemical is probably combustible.
[Chemical Properties]

light yellow liquid
[Uses]

Methyl vinyl sulfone has been used:
  • as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry
  • in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric
  • in Heck vinylation of aryl halides
[Purification Methods]

Pass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.]
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl vinyl sulfone(3680-02-2)MS
Methyl vinyl sulfone(3680-02-2)1HNMR
Methyl vinyl sulfone(3680-02-2)13CNMR
Methyl vinyl sulfone(3680-02-2)IR1
Methyl vinyl sulfone(3680-02-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl vinyl sulfone, stabilized, 98%(3680-02-2)
[Alfa Aesar]

Methyl vinyl sulfone, 98%, stab. with 200ppm 4-tert-butylphenol(3680-02-2)
[Sigma Aldrich]

3680-02-2(sigmaaldrich)
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