ChemicalBook--->CAS DataBase List--->583-68-6

583-68-6

583-68-6 Structure

583-68-6 Structure
IdentificationMore
[Name]

2-Bromo-4-methylaniline
[CAS]

583-68-6
[Synonyms]

2-BROMO-4-METHYLANILINE
2-BROMO-4-METHYL-PHENYLAMINE
2-BROMO-P-TOLUIDINE
3-BROMO-4-AMINOTOLUENE
4-AMINO-3-BROMOTOLUENE
4-AMINO-3-BROMTOLUOL
AKOS BBS-00003652
2-bromo-4-methyl-benzenamin
2-Bromo-4-methylbenzenamine
2-Bromo-4-toluidine
2-bromo-p-toluidin
2-bromotoluidine
4-methyl-2-bromoaniline
o-Bromo-p-toluidine
p-Toluidine, 2-bromo-
2-Bromo-4-methylaniline, (4-Amino-3-bromotoluene
2-Bromo-4-methylaniline,99% (4-Amino-3-bromtoluol)
2-Bromo-p-toluid
4-Amino-3-bromotoluene~2-Bromo-p-toluidine
2-Bromo-4-methylanline
[EINECS(EC#)]

209-515-7
[Molecular Formula]

C7H8BrN
[MDL Number]

MFCD00007635
[Molecular Weight]

186.05
[MOL File]

583-68-6.mol
Chemical PropertiesBack Directory
[Appearance]

clear light yellow to brown liquid
[Melting point ]

14-16 °C (lit.)
[Boiling point ]

240 °C (lit.)
[density ]

1.5 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.602(lit.)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

Chloroform (Slightly)
[form ]

Oil
[pka]

2.97±0.10(Predicted)
[color ]

Dark Yellow to Dark Beige
[Specific Gravity]

1.500
[Water Solubility ]

Insoluble in water.
[BRN ]

1931711
[Stability:]

Air Sensitive
[InChIKey]

UVRRJILIXQAAFK-UHFFFAOYSA-N
[CAS DataBase Reference]

583-68-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, 2-bromo-4-methyl-(583-68-6)
[EPA Substance Registry System]

583-68-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R33:Danger of cumulative effects.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

XU4300000
[Hazard Note ]

Irritant/Toxic
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29214300
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium sulfite-->p-Acetotoluidide-->N-Acetyl-p-toluidine -->Silanamine, 1,1,1-trimethyl-N-(4-methylphenyl)--->methyl N-(2-bromo-4-methylphenyl)carbamate-->2-BROMO-4-METHYLANILINE HYDROCHLORIDE-->2-BroMo-4-Methyl-1-nitro-benzene-->2-Bromo-4-methylphenylboronic acid-->2-BROMO-N-METHYLANILINE 95
[Preparation Products]

3-Bromotoluene-->2-BROMO-4-METHYLBENZONITRILE-->5-Methylindole-->2-Bromo-4-methylphenol-->2'-BROMO-4'-METHYLACETANILIDE-->5-METHYLINDOLE-3-CARBOXYLIC ACID METHYL ESTER-->5-METHYL-2-PHENYLINDOLE-->2-Chloro-6-methylbenzothiazole-->2-Amino-5-Methyl-Benzonitrile-->2-Bromo-4-methylbenzaldehyde
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Amino-3-bromotoluene(583-68-6).msds
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow to brown liquid
[Uses]

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.
[General Description]

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Bromo-4-methylaniline(583-68-6)MS
2-Bromo-4-methylaniline(583-68-6)1HNMR
2-Bromo-4-methylaniline(583-68-6)13CNMR
2-Bromo-4-methylaniline(583-68-6)IR1
2-Bromo-4-methylaniline(583-68-6)IR2
2-Bromo-4-methylaniline(583-68-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Bromo-4-methylaniline, 98%(583-68-6)
[Alfa Aesar]

2-Bromo-4-methylaniline, 99%(583-68-6)
[TCI AMERICA]

2-Bromo-4-methylaniline,>98.0%(GC)(583-68-6)
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