Dehydracetsäure

Dehydroacetic acid Struktur
520-45-6
CAS-Nr.
520-45-6
Bezeichnung:
Dehydracetsäure
Englisch Name:
Dehydroacetic acid
Synonyma:
DHA;dhaa;3-ACETYL-6-METHYL-2H-PYRAN-2,4(3H)-DIONE;2H-Pyran-2-one, 3-acetyl-4-hydroxy-6-methyl-;Geogard(R) 221;DEHYDRANONE;Biocide 470F;Geogard(R) 361;Geogard(R) 111A;DEHYDRACETSAEURE
CBNumber:
CB0139753
Summenformel:
C8H8O4
Molgewicht:
168.15
MOL-Datei:
520-45-6.mol

Dehydracetsäure Eigenschaften

Schmelzpunkt:
111-113 °C (lit.)
Siedepunkt:
270 °C (lit.)
Dichte
1.1816 (rough estimate)
Dampfdruck
0.001 hPa (20 °C)
Brechungsindex
1.4611 (estimate)
Flammpunkt:
157°C
storage temp. 
Store below +30°C.
Löslichkeit
2g/l
Aggregatzustand
Fine Crystalline Powder
pka
5.53±0.40(Predicted)
Farbe
Light yellow or cream
PH
4 (2g/l, H2O, 20℃)
Wasserlöslichkeit
500mg/L at 25℃
Merck 
14,2865
BRN 
6129
Stabilität:
Stable. Incompatible with oxidizing agents, bases, reducing agents.
InChIKey
PGRHXDWITVMQBC-UHFFFAOYSA-N
LogP
0.78 at 20℃
CAS Datenbank
520-45-6(CAS DataBase Reference)
NIST chemische Informationen
Dehydroacetic Acid(520-45-6)
EPA chemische Informationen
3-Acetyl-6-methyl-2H-pyran-2,4(3H)-dione (520-45-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 22
S-Sätze: 22-26
WGK Germany  1
RTECS-Nr. UP8050000
Selbstentzündungstemperatur 336 °C
TSCA  Yes
HS Code  29322980
Giftige Stoffe Daten 520-45-6(Hazardous Substances Data)
Toxizität LD50 orally in rats: 1000 mg/kg (Spencer)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P270 Bei Gebrauch nicht essen, trinken oder rauchen.
P301+P312 BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P501 Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Dehydracetsäure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R22:Gesundheitsschädlich beim Verschlucken.

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.

Chemische Eigenschaften

Dehydroacetic acid is a white to cream-coloured powder that is only very slightly soluble in water (less than 0.1 %). However, the sodium salt hydrate (CSH7Na04.H20) has a solubility of 33% in water at 25°C, and 48% in propylene glycol. The acid is 22% soluble in acetone, 18% in benzene, and I g dissolves in about 35 ml of ethanol.It is used to reduce pickle bloating, and as a pesticide and preservative for squash and strawberries. Its permissible use level is 65ppm.
Dehydroacetic acid is one of the food additives found in red wine and was determined by ultra-fast liquid chromatography-tandem quadrupole mass spectrometry (UFLC-MS/MS).
To assay dehydroacetic acid, add 500 mg to a 250-ml Erlenmeyer flask and dissolve in 75 ml of neutral alcohol. Following the addition of phenolphthalein T.S., titrate with 0.1 N NaOH to a pink end-point that persists for at least 30 s. Each ml of 0.1 N NaOH = 16.82 mg of dehydroacetic acid (National Academy of Sciences, 1963).
Dehydroacetic acid is a synthetic chemical (no plant-based preservatives that meet our efficacy standards currently exist) that is considered to be a low hazard for human health and for the environment.

Verwenden

Dehydroacetic acid (DHS) is used as stabilizer for cosmetic and pharmaceutical products due to its fungicide and bactericide activity, as additive for PVC-stabilizers and for the syntheses of veterinary medicines. Product Data Sheet

Allgemeine Beschreibung

Dehydroacetic acid is a pyrone derivative, that is typically synthesized by the base-catalyzed dimerization of diketene. It is used as a preservative in pharmaceutical, food and cosmetic products.
Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards.

Sicherheitsprofil

Poison by ingestion. Moderately toxic by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.

Dehydracetsäure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Dehydracetsäure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 439)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
sales@tnjchem.com China 34572 58
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+8613288715578
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+undefined86-15315557071
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+8613343047651
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Capot Chemical Co.,Ltd.
571-85586718 +8613336195806
sales@capotchem.com China 29797 60
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+86-371-66670886
info@dakenam.com China 15956 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21689 55
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008657128800458; +8615858145714
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Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763
info@tnjchem.com China 2989 55

520-45-6(Dehydracetsäure)Verwandte Suche:


  • 3-Acetyl-6-methyl-2H-pyran-2,4(3H)-dione. enol form
  • 3-acetyl-6-methyl-2h-pyran-2,4(3h)-dione.enolform
  • 3-acetyl-6-methyl-2h-pyran-2,4(3h)-dioneenolform
  • 3-acetyl-6-methyl-2h-pyran-4(3h)-dione
  • 3-Acetyl-6-Methyldihydropyrandione-2,4
  • 3-Acetyl-6-methylpyrandione-2,4
  • 4(3H)-dione,3-acetyl-6-methyl-2H-Pyran-2
  • 4-Hexenoic acid, 2-acetyl-5-hydroxy-3-oxo-, delta-lactone
  • 4-hexenoicacid,2-acetyl-5-hydroxy-3-oxo,lactone
  • Geogard(R) 111A
  • Benzyl alcohol (and) dehydroacetic acid
  • Geogard(R) 361
  • Dehydroacetic acid ,98%
  • Acetylmethylpyrandion
  • Acetylmethylpyronone
  • Dehydroacetoic acid
  • 3-Aceto-6-methyl-2-pyronone
  • Dehydroacetic Acid (200 mg)
  • Dehydroacetic acid, 98% 100GR
  • Dehydroacetic acid, 98% 5GR
  • -Acetyl-6-methyl-pyran-2,4-dione
  • Dehydroacetic acid >=98.0% (T)
  • dehydro-aceticaci
  • -Hexenoic acid, 2-acetyl-5-hydroxy-3-oxo-, d-lactone
  • Kyselina dehydroacetova
  • kyselinadehydroacetova
  • Methylacetopyronone
  • 3-Acetyl-6-methyl-2-pyranone
  • Dehydroactic acid(DHA)
  • 3-Acetyl-6-methyl-pyran-2,4-dione
  • DEHYDROACETIC ACID FREE ACID CRYSTALLINE
  • PYRAN-2,4-DIONE,3-ACETYL-6-METHYL
  • 3-Acetyl-6-methyl-2H-pyran-2,4(3H)dion
  • DEHYDRACETSAEURE
  • 3-acetyl-6-methyl-2H-pyran-2,4(3H)-dione dehydracetic acid
  • 2-Acetyl-5-hydroxy-3-oxo-4-hexenoic acid δ-lactone, 3-Acetyl-4-hydroxy-6-methyl-2-pyrone
  • 3-ACETYL-3,4-DIHYDRO-6-METHYL-2H-PYRAN-2,4-DIONE
  • 3-ACETYL-4-HYDROXY-6-METHYL-2H-PYRAN-2-ONE
  • 3-ACETYL-4-HYDROXY-6-METHYL-2-PYRONE
  • 3-ACETYL-6-METHYL-2H-PYRONE-2,4-(3H)-DIONE
  • 2-ACETYL-5-HYDROXY-3-OXO-4-HEXENOIC ACID DELTA-LACTONE
  • 2-ACETYL-5-HYDROXY-3-OXO-4-HEXENOIC ACID D-LACTONE
  • 2-ACETYL-5-HYDROXY-3-OXO-4-HEXENOIC ACID GAMMA-LACTONE
  • 2-acetyl-5-hydroxy-3-oxo-4-hexenoicacidelta-lactone
  • 2-Acetyl-5-hydroxy-3-oxo-4-hexenoicacid-lactone
  • 2H-Pyran-2,4(3H)-dione, 3-acetyl-6-methyl-
  • 3-acetyl-4-hydroxy-6-methyl-2h-pyran-2-on
  • 3-Acetyl-4-hydroxy-6-methyl-2-pyrone cyclic ketone
  • 3-Acetyl-6-methyl-2,3-dihydropyran-2,4-dione
  • 3-Acetyl-6-methyl-2,4-pyrandione
  • 3-Acetyl-6-methyl-2H-pyran-2,4(3H)-dione, ion(1-)
  • DEHYDRACETIC ACID
  • DEHYDRANONE
  • DEHYDROACETIC ACID
  • LABOTEST-BB LT00053173
  • DA,Dehydroacetic
  • Biocide 470F
  • Dehydroacetic Acid >
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