4-NITROSODIPHENYLAMINE
- CAS No.
- 156-10-5
- Chemical Name:
- 4-NITROSODIPHENYLAMINE
- Synonyms
- TKB;naugardtkb;NCI-C02244;Naugard tkb;4-Niinylamine;4-Nitrosophenylamine;nitrousdiphenylamide;p-Nitrosodifenylamin;P-NITROSODIPHENYLAMINE;4-NITROSODIPHENYLAMINE
- CBNumber:
- CB3105429
- Molecular Formula:
- C12H10N2O
- Molecular Weight:
- 198.22
- MDL Number:
- MFCD00002062
- MOL File:
- 156-10-5.mol
| Melting point | 144 °C (dec.)(lit.) |
|---|---|
| Boiling point | 335.53°C (rough estimate) |
| Density | 1.1447 (rough estimate) |
| refractive index | 1.6330 (estimate) |
| storage temp. | -20°C Freezer, Under inert atmosphere |
| solubility | Chloroform (Slightly, Heated, Sonicated), DMSO (Slightly, Sonicated) |
| form | Solid |
| pka | -3.56±0.20(Predicted) |
| color | Green plates with bluish luster (from benzene) orsteel-blue prisms or plates (from ether + H2O) |
| Merck | 14,6639 |
| CAS DataBase Reference | 156-10-5(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | F7052989CV |
| Proposition 65 List | p-Nitrosodiphenylamine |
| IARC | 3 (Vol. 27, Sup 7) 1987 |
| EPA Substance Registry System | p-Nitrosodiphenylamine (156-10-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-36/38 | |||||||||
| Safety Statements | 26-36/37 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | JK0175000 | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29214200 | |||||||||
| Toxicity | LD50 intravenous in mouse: 178mg/kg | |||||||||
| NFPA 704 |
|
4-NITROSODIPHENYLAMINE price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | N0263 | 4-Nitrosodiphenylamine >97.0%(HPLC) | 156-10-5 | 25g | $249 | 2024-03-01 | Buy |
| AK Scientific | 5941AF | 4-Nitrosodiphenylamine | 156-10-5 | 25g | $367 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0012170 | 4-NITROSODIPHENYLAMINE 95.00% | 156-10-5 | 1G | $626.08 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0012170 | 4-NITROSODIPHENYLAMINE 95.00% | 156-10-5 | 5G | $818.03 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0012170 | 4-NITROSODIPHENYLAMINE 95.00% | 156-10-5 | 10G | $1137.05 | 2021-12-16 | Buy |
4-NITROSODIPHENYLAMINE Chemical Properties,Uses,Production
Chemical Properties
TKB is a black powder or a green plate-like material with a bluish luster.
Chemical Properties
dark blue to black powder
Uses
4-?Nitrosodiphenylamine is used in organic synthesis such as in the preparation of 1-(Phenylamino)pseudo-mauveine water soluble dye. Potential mutagenic compound.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
Uses
Has been used as retardant in vulcanizing rubber.
Definition
ChEBI: Para-Nitrosodiphenylamine is a member of benzenes.
Synthesis Reference(s)
The Journal of Organic Chemistry, 32, p. 153, 1967 DOI: 10.1021/jo01277a038
General Description
Green plates with bluish luster or a black powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-NITROSODIPHENYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. May react with strong oxidizing agents .
Hazard
Questionable carcinogen.
Fire Hazard
Flash point data for 4-NITROSODIPHENYLAMINE are not available; however, 4-NITROSODIPHENYLAMINE is probably combustible.
Safety Profile
Poison by intravenous route. Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Moderately toxic by ingestion. Mutation data reported. An eye irritant. When heated to decomposition it emits toxic fumes of NOx. See also NNITROSO COMPOUNDS and AMINES.
Potential Exposure
Used as a chemical intermediate for dyes and pharmaceuticals; in making monomers; and vulcanizing rubber.
Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Purification Methods
The amine forms dark green crystals from EtOH or *C6H6 (m 143o). It has UV at max 421nm (EtOH) and is used for detecting Pd and Rh. It is highly toxic and a possible carcinogen.[Beilstein 12 H 207, 12 II 122, 12 III 347, 12 IV 1860..]
Incompatibilities
Nitrated organics range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction. Reaction with aliphatic amines can release carcinogenic nitrosamines. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. 4-nitrosodiphenylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrideds and active metals. May react with strong oxidizing agents.
4-NITROSODIPHENYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178 +86-85511178 | peter68@ptchemgroup.com | China | 35453 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 50000 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33349 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9020 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
View Lastest Price from 4-NITROSODIPHENYLAMINE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-02-01 | 4-Nitrosodiphenylamine
156-10-5
|
US $1.00 / KG | 1KG | Min98% HPLC | g/kg/ton | Career Henan Chemical Co |
-
- 4-Nitrosodiphenylamine
156-10-5
- US $1.00 / KG
- Min98% HPLC
- Career Henan Chemical Co
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