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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

CAS No.
37891-79-5
Chemical Name:
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Synonyms
BIS(METHYLTHIO)METHYLTRIMETHYLSILANE;TRIMETHYLBIS(METHYLTHIO)METHYLSILANE;BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE;Silane, [bis(methylthio)methyl]trimethyl-;Bis(methylthio)(trimethylsilyl)methane >Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
CBNumber:
CB3275106
Molecular Formula:
C6H16S2Si
Molecular Weight:
180.41
MDL Number:
MFCD01631301
MOL File:
37891-79-5.mol
Last updated:2023-06-08 17:06:36

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Properties

Boiling point 82 °C(Press: 10.0 Torr)
Density 0.941±0.06 g/cm3(Predicted)
refractive index 1.5060-1.5100
solubility insol H2O; sol organic solvents.
form clear liquid
color Colorless to Light yellow to Light orange

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H227-H315-H319
Precautionary statements  P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P403+P235-P501
HS Code  2931.90.9010
NFPA 704
0
1 0

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B2004 Bis(methylthio)(trimethylsilyl)methane >98.0%(GC) 37891-79-5 1g $99 2024-03-01 Buy
TRC B102786 Bis(methylthio)(trimethylsilyl)methane 37891-79-5 10mg $45 2021-12-16 Buy
Biosynth Carbosynth FB61175 Bis(methylthio)(trimethylsilyl)methane 37891-79-5 250mg $100 2021-12-16 Buy
American Custom Chemicals Corporation ORS0001338 BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE 95.00% 37891-79-5 1G $257.46 2021-12-16 Buy
AK Scientific 7236AL Bis(methylthio)(trimethylsilyl)methane 37891-79-5 5g $664 2021-12-16 Buy
Product number Packaging Price Buy
B2004 1g $99 Buy
B102786 10mg $45 Buy
FB61175 250mg $100 Buy
ORS0001338 1G $257.46 Buy
7236AL 5g $664 Buy

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Chemical Properties,Uses,Production

Physical properties

bp 67–70°C/10 mmHg.

Uses

Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.
The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.Uses of Bis(methylthio)(trimethylsilyl)methane

Preparation

prepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.

37891-79-5 synthesis

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials

Raw materials

Preparation Products

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Suppliers

Global( 46)Suppliers
Supplier Tel Email Country ProdList Advantage
Career Henan Chemica Co
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Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Zhejiang J&C Biological Technology Co.,Limited
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PT CHEM GROUP LIMITED
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GIHI CHEMICALS CO.,LIMITED
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Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40240 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
TRIMETHYLBIS(METHYLTHIO)METHYLSILANE Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane BIS(METHYLTHIO)METHYLTRIMETHYLSILANE BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Silane, [bis(methylthio)methyl]trimethyl- Bis(methylthio)(trimethylsilyl)methane > 37891-79-5 C6H16S2Si Si-(C)4 Compounds Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Sulfur Compounds (for Synthesis) Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Sulfur Compounds (for Synthesis) Synthetic Organic Chemistry