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Diphenylmercury

CAS No.
587-85-9
Chemical Name:
Diphenylmercury
Synonyms
difenylrtut;diphenylmercure;diphenyl-mercur;DIPHENYLMERCURY;MERCURY DIPHENYL;mercury(ii)diphenyl;diphenylmercury(ii);Benzene, mercuriodi-;Diphenylmercury,min.96%;Diphenylmercury, min. 96%
CBNumber:
CB3853887
Molecular Formula:
C12H10Hg
Molecular Weight:
354.8
MDL Number:
MFCD00002998
MOL File:
587-85-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Diphenylmercury Properties

Melting point 121-124 °C (lit.)
Boiling point >306°C
Density 2.32 g/mL at 25 °C (lit.)
Flash point >306°C
storage temp. Poison room
Water Solubility Insoluble in water.
BRN 637234
Exposure limits ACGIH: TWA 0.1 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
CAS DataBase Reference 587-85-9(CAS DataBase Reference)
FDA UNII 9JF9FUI57J
EPA Substance Registry System Mercury, diphenyl- (587-85-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H300-H310-H330-H400-H300+H310+H330-H373-H410
Precautionary statements  P260-P262-P280-P302+P352+P310-P304+P340+P310-P264-P273-P284-P301+P310-P301+P310a-P304+P340-P320-P330-P405-P501a
Hazard Codes  T+,N
Risk Statements  26/27/28-33-50/53
Safety Statements  13-28-36-45-60-61
RIDADR  UN 2026 6.1/PG 3
WGK Germany  3
RTECS  OW3150000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
NFPA 704
0
4 0

Diphenylmercury price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation OGM0000730 DIPHENYLMERCURY(II) 95.00% 587-85-9 10G $1179.16 2021-12-16 Buy
Product number Packaging Price Buy
OGM0000730 10G $1179.16 Buy

Diphenylmercury Chemical Properties,Uses,Production

Chemical Properties

White to beige powder

Safety Profile

Moderately toxic by ingestion. Incompatible with nonmetal oxides. When heated to decomposition it emits toxic fumes of Hg. See also MERCURY COMPOUNDS.

Purification Methods

Sublime it, then crystallise it from nitromethane or ethanol. If phenylmercuric halides are present, they can be converted to phenylmercuric hydroxide which, being much more soluble, remain in the alcohol or *benzene used for crystallisation. Thus, crude material (10g) is dissolved in warm ethanol (ca 150mL) and shaken with moist Ag2O (ca 10g) for 30minutes, then heated under reflux for 30minutes and filtered hot. Concentrating the filtrate by evaporation gives diphenylmercury, which is then recrystallised from *benzene [Blair et al. J Chem Soc 3174 1959]. [Beilstein 16 IV 1702.] TOXIC.

Diphenylmercury Preparation Products And Raw materials

Raw materials

Preparation Products

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mercury(ii)diphenyl Diphenyl mercury (aryl compound) Diphenylmercury, min. 96% DIPHENYLMERCURY MERCURY DIPHENYL Benzene, mercuriodi- difenylrtut diphenyl-mercur diphenylmercure DIPHENYLMERCURY PESTANAL, 250 MG Diphenylmercury,min.96% diphenylmercury(ii) Diphenylmercury ISO 9001:2015 REACH Nicotinic Acid Impurity 50 587-85-9 C6H52Hg C12H10Hg Mercury Catalysis and Inorganic Chemistry