Hexamethyldistannane
- CAS No.
- 661-69-8
- Chemical Name:
- Hexamethyldistannane
- Synonyms
- HEXAMETHYLDITIN;1,1,1,2,2,2-Hexamethyldistannane;HEXAMETHYLDITIN(IV);1,1,1,2,2,2-Hexamethyl-distannane;TD 5032;td-5032;NSC-227328;((CH3)3Sn)2;pennsalttd5032;Hexamethlyditin
- CBNumber:
- CB4407230
- Molecular Formula:
- C6H18Sn2
- Molecular Weight:
- 327.63
- MDL Number:
- MFCD00008277
- MOL File:
- 661-69-8.mol
Melting point | 23-24 °C (lit.) |
---|---|
Boiling point | 182 °C/756 mmHg (lit.) |
Density | 1.58 g/mL at 20 °C (lit.) |
refractive index |
n |
Flash point | 142 °F |
storage temp. | Inert atmosphere,Room Temperature |
form | solid |
Specific Gravity | 1.570 |
color | Colourless |
Water Solubility | Not miscible or difficult to mix in water. |
Sensitive | Air Sensitive |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 3600327 |
Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
InChIKey | CCRMAATUKBYMPA-UHFFFAOYSA-N |
CAS DataBase Reference | 661-69-8(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | DSR4SPH97E |
NIST Chemistry Reference | Hexamethylditin(661-69-8) |
EPA Substance Registry System | Distannane, hexamethyl- (661-69-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H300+H310+H330-H410 | |||||||||
Precautionary statements | P260-P262-P273-P280-P302+P352+P310-P304+P340+P310 | |||||||||
Hazard Codes | T+,N | |||||||||
Risk Statements | 26/27/28-50/53 | |||||||||
Safety Statements | 26-27-28-45-60-61-28A | |||||||||
RIDADR | UN 3146 6.1/PG 2 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | WH8280000 | |||||||||
F | 10-23 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
Toxicity | LD50 oral in rat: 7690ug/kg | |||||||||
NFPA 704 |
|
Hexamethyldistannane price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 288020 | Hexamethylditin 99% | 661-69-8 | 1g | $65.6 | 2024-03-01 | Buy |
Sigma-Aldrich | 288020 | Hexamethylditin 99% | 661-69-8 | 5g | $102.6 | 2024-03-01 | Buy |
TCI Chemical | H1312 | Hexamethylditin >98.0%(GC) | 661-69-8 | 1g | $38 | 2024-03-01 | Buy |
TCI Chemical | H1312 | Hexamethylditin >98.0%(GC) | 661-69-8 | 5g | $116 | 2024-03-01 | Buy |
Alfa Aesar | A17638 | Hexamethylditin, 97% | 661-69-8 | 1g | $59.4 | 2023-06-20 | Buy |
Hexamethyldistannane Chemical Properties,Uses,Production
Description
It has been generally used as raw materials for producing other compounds in organic synthesis. For example, it can react with 1,3-dienes highly regioand stereo-selectively in the presence of a catalytic amount of bis(dibenzylideneacetone)palladium to afford dimerization-double-stannation adducts in high yields.1 The synthesis of allytrimethylstannanes with high yields was demonstrated by reaction of hexamethyldistanne with a broad range of allylic compounds including allyl acetates and allyl halides in the presence of palladium complexes.2 By using this product, the direct stannylation of halopyridines and bipyridines can be accomplished by Pd catalysis.3 Besides, the addition of hexamethyldistannane to 1-alkynes was shown to yield the (Z)-1,2-Bis(Trimethylstannyl)-1-Alkenes in the presence of Pd complex.4
Reference
- Tsuji, Y.; Kakehi, T., PALLADIUM-CATALYZED DIMERIZATION DOUBLE STANNATION OF 1,3-DIENES USING HEXAMETHYLDISTANNANE. J. Chem. Soc.-Chem. Commun. 1992, 1000-1001.
- Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P., REACTIONS OF HEXAMETHYLDISTANNANE WITH ALLYL ACETATES AND ALLYL HALIDES CATALYZED BY PALLADIUM COMPLEXES. Bulletin of the Academy of Sciences of the Ussr Division of Chemical Science 1984, 33, 588-594.
- Benaglia, M.; Toyota, S.; Woods, C. R.; Siegel, J. S., Synthesis of pyridylstannanes from halopyridines and hexamethyldistannane with catalytic palladium. Tetrahedron Lett. 1997, 38, 4737-4740.
- Mitchell, T. N.; Amamria, A.; Killing, H.; Rutschow, D., SYNTHESIS OF (Z)-1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES BY PLATINUM-CATALYZED ADDITION OF HEXAMETHYLDISTANNANE TO 1-ALKYNES. J. Organomet. Chem. 1983, 241, C45-C47.
Chemical Properties
Clear colorless liquid
Uses
It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.
Uses
Agricultural chemical.
Hazard
A poison by ingestion.
Purification Methods
Wash it with H2O and extract with *C6H6, dry by filtering through powdered Na2SO4, remove *C6H6 on a rotary evaporator and fractionally distil the oily residue under vacuum (b 85-88o/45mm). It boils at ca 182o at atmospheric pressure, but it cannot be distilled in air because the hot vapours flash in the condenser. [Kraus & Session J Am Chem Soc 47 2361 1925, Morris & Selwood J Am Chem Soc 63 2509 1941, Pedley et al. Trans Faraday Soc 53 1612 1957, Beilstein 4 IV 4346.]
Hexamethyldistannane Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12711 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9126 | 58 |
Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
Aston Chemical | 13000000000 | sales@astonchem.com | United States | 1634 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
View Lastest Price from Hexamethyldistannane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2020-03-10 | Hexamethyldistannane
661-69-8
|
US $16.00 / KG | 1KG | 98% | 1kg, 10kg, 50kg | Career Henan Chemical Co |
- Hexamethyldistannane
661-69-8
- US $16.00 / KG
- 98%
- Career Henan Chemical Co