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Pyridinium chlorochromate

Pyridinium chlorochromate Structure
Pyridinium chlorochromate structure
CAS No.
26299-14-9
Chemical Name:
Pyridinium chlorochromate
Synonyms
PCC;pyridinium;dipyridinium dichromate;chromate(1-),chlorotrioxo-,(beta-4)-,hydrogen,compd.withpyridine(1:1);The PCC;Urine Luck;orochromate;Pyridinium chL;Corey's reagent;Pyridinium chlorochr
CBNumber:
CB4667463
Molecular Formula:
C5H6ClCrNO3
Molecular Weight:
215.55
MDL Number:
MFCD00013106
MOL File:
26299-14-9.mol
MSDS File:
SDS
Last updated:2023-05-09 17:25:19
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Pyridinium chlorochromate Properties

Melting point 205-208 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran.
form Crystalline Powder
color Orange
Sensitive Moisture Sensitive
Merck 14,7974
BRN 7054643
Exposure limits OSHA: Ceiling 0.1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3
Stability Stable. May react with easily oxidized materials. Incompatible with reducing agents, combustible material, metals, strong reducing agents.
InChIKey LEHBURLTIWGHEM-UHFFFAOYSA-N
CAS DataBase Reference 26299-14-9(CAS DataBase Reference)
FDA UNII DTV5HU1N27
EPA Substance Registry System Pyridinium chlorochromate (26299-14-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS03,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H272-H317-H350i-H410
Precautionary statements  P201-P210-P273-P280-P302+P352-P308+P313
Hazard Codes  O,T,N
Risk Statements  49-8-43-50/53-20/21/22
Safety Statements  53-45-60-61-37-24-17-44-36/37/39-22
RIDADR  UN 1479 5.1/PG 2
WGK Germany  2
TSCA  Yes
HazardClass  5.1
PackingGroup  III
HS Code  29333990
NFPA 704
1
2 2
OX

Pyridinium chlorochromate price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 190144 Pyridinium chlorochromate 98% 26299-14-9 25g $35.3 2024-03-01 Buy
Sigma-Aldrich 190144 Pyridinium chlorochromate 98% 26299-14-9 100g $89.1 2024-03-01 Buy
TCI Chemical P0930 Pyridinium Chlorochromate >98.0%(T) 26299-14-9 25g $19 2024-03-01 Buy
TCI Chemical P0930 Pyridinium Chlorochromate >98.0%(T) 26299-14-9 100g $45 2024-03-01 Buy
Alfa Aesar A11752 Pyridinium chlorochromate, 98% 26299-14-9 25g $27.65 2024-03-01 Buy
Product number Packaging Price Buy
190144 25g $35.3 Buy
190144 100g $89.1 Buy
P0930 25g $19 Buy
P0930 100g $45 Buy
A11752 25g $27.65 Buy

Pyridinium chlorochromate Chemical Properties,Uses,Production

Chemical Properties

Pyridinium chlorochromate is orange crystalline powder

Uses

Oxidizing agent in organic synthesis.
PCC is pyridinium chlorochromate; PDC is pyridinium dichromate. Both are used in dichloromethane.

Uses

Pyridinium chlorochromate is usually used to oxidize an allylic methylene group.
Oxidation of primary alcohols to aldehydes
Oxidation of primary alcohols to aldehydes
Pyridinium dichromate (PDC) or pyridinium chlorochromate (PCC) in anhydrous media such as dichloromethane oxidizes primary alcohols to aldehydes while avoiding overoxidation to carboxylic acids.

Uses

Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

Reactions

Pyridinium chlorochromate (PCC) is a widespread used oxidation reagent but lacks of selectivity with unsaturated compounds. Furthermore, the workup procedure is quite tedious. Absorption of PCC onto silica gel improves the oxidation but then a reagent excess is necessary to reach appropriate rates. These drawbacks can be overcome by sonication leading to short reaction times and only an small excess of 1.2.-1.5 eq. of PCC is required. Using this reagent has been used to oxidise borneol to camphor in 85% yield.
Pyridinium chlorochromate Reaction

Purification Methods

Dry it in a vacuum for 1hour. It is not hygroscopic and can be stored for extended periods at room temperature without change. If the purity is very suspect, it can be readily prepared. [Corey & Scuggs Tetrahedron Lett 2647 1975, Piancatelli et al. Synthesis 245 1982.] (Possible CARCINOGEN.) § Available commercially on a polymer support.

Pyridinium chlorochromate Preparation Products And Raw materials

Raw materials

Preparation Products

Tetrahydropyran-4-carbaldehyde 4-(MORPHOLIN-4-YLMETHYL)-1,3-THIAZOL-2-AMINE 2-[4-(TRIFLUOROMETHYL)PHENYL]-1,3-THIAZOLE-4-CARBALDEHYDE TERT-BUTYL 4-(4-FORMYL-1,3-THIAZOL-2-YL)TETRAHYDRO-1(2H)-PYRIDINECARBOXYLATE TERT-BUTYL 4-(5-FORMYLPYRID-2-YL)PIPERAZINE-1-CARBOXYLATE
2,5-DIBROMONICOTINALDEHYDE 3-(2,6-DICHLOROPHENYL)-5-METHYLISOXAZOLE-4-CARBALDEHYDE 1-tert-Butoxycarbonyl-4-piperidinecarboxaldehyde 1-(2,6-DIFLUOROPYRIDIN-3-YL)PROPAN-1-ONE 1,3-DIMETHYL-1H-PYRAZOLE-5-CARBALDEHYDE
4-METHYL-2-[4-(TRIFLUOROMETHYL)PHENYL]-1,3-THIAZOLE-5-CARBALDEHYDE N-BOC-L-Prolinal 1-TERT-BUTYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-4-CARBALDEHYDE Cyclopropanecarboxaldehyde ,5-Dihydro-5-methyl-6-[4-(4-oxo-1(4H)-pyridinyl)phenyl]-1,2,4-triazin-3(2H)-one
2-PHENYL-1,3-THIAZOLE-4-CARBALDEHYDE 2,4-DIPHENYL-1,3-THIAZOLE-5-CARBALDEHYDE 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carbaldehyde 3-(4-NITRO-PHENYL)-PROPIONALDEHYDE 5-CHLORO INDAZOLE-3-CARBOXALDEHYDE
TERT-BUTYL 4-(5-FORMYL-4-METHYL-1,3-THIAZOL-2-YL)PIPERIDINE-1-CARBOXYLATE 3-(TRIFLUOROMETHYL)-1-METHYL-1H-PYRAZOLE-4-CARBALDEHYDE 3-(2-METHOXY-PHENYL)-PROPIONALDEHYDE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBALDEHYDE

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Pyridinium chlorochromate Suppliers

Global( 448)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
Shanghai Yingrui Biopharma Co., Ltd. 		+86-21-33585366 - 03@ sales03@shyrchem.com CHINA 738 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32686 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49391 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
Shanghai Yingrui Biopharma Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
Richest Group Ltd 		58

Related articles

View Lastest Price from Pyridinium chlorochromate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Pyridinium chlorochromate pictures 2023-05-10 Pyridinium chlorochromate
26299-14-9
 US $100.00 / kg 1kg 99% 100 tons Hebei Duling International Trade Co. LTD
Pyridinium chlorochromate pictures 2022-05-20 Pyridinium chlorochromate
26299-14-9
 US $300.00 / G 25G 98% 500KG GLR Innovations
Pyridinium chlorochromate (PCC) pictures 2021-10-30 Pyridinium chlorochromate (PCC)
26299-14-9
 US $10.00 / Kg/Bag 1Kg/Bag 99% 20 Tons Hebei Zhanyao Biotechnology Co. Ltd

Pyridinium chlorochromate Spectrum

Pyridinium chlorochromate(26299-14-9)1HNMRPyridinium chlorochromate(26299-14-9)IR1Pyridinium chlorochromate(26299-14-9)IR2Pyridinium chlorochromate(26299-14-9)Raman

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PYRIDINIUM CHLOROCHROMATE Pyridine, (T-4)-chlorotrioxochromate(1-) Pyridine, chlorotrioxochromate(1-) Urine Luck PYRIDINIUM CHLOROCHROMATE, CA. 20 WT. % ON BASIC ALUMINA PyridiniumChlirochromate PyridinumChlorochromate PyridiniumChlorochromate99% Pyridinium Chlorochromate 99% Pyridiniumchlorochromate,98% Chromate(1-), chlorotrioxo-, (T-4)-, hydrogen, compd. with pyridine (1:1) Pyridinechloro-chromate Pyridinium chlorochr Pyridine·chlorochromic acid Pyridinium chlorochromate, PCC CrO3*pyridiniuM hydrochloride PYRIDINIUMCHLCHROMAT S PyridiuM ChloroforMate PyridiniuM chlorochroMate, 98% 100GR PyridiniuM chlorochroMate, 98% 25GR PyridiniuM chlorochroMate, 98% 500GR PCC)PyridiniuM chlorochro Pyridinium chloro(oxido)dioxochromium, PCC The PCC Pyridinium Chlorochromate complex Chromate(1-), chlorotrioxo-, (T-4)-, hydrogen, compound with pyridine (1:1) Corey's reagent orochromate Pyridinium chL PyridiniumChlorochromate> Pyridine chlorochromate(PCC) Pyridinium chlorochromate ISO 9001：2015 REACH Pyridinium Chlorochromate (PCC) extrapure, 98% PYRIDINIUM CHLOROCHROMATE Extra Pure PCC chromate(1-),chlorotrioxo-,(beta-4)-,hydrogen,compd.withpyridine(1:1) pyridinium dipyridinium dichromate Pyidinium chlorochromate pyridium chlorocromate (98.14%) pyridium chlorocromate 26299-14-9 26299-04-9 26299-14-19 C5H5NClCrO3H C5H5NHCrO3Cl C5H6ClCrNO3 C5H6NClCrO3 Pyridinium Compounds Cr (Chromium) Compounds Transition Metal Compounds Oxidation Classes of Metal Compounds Specialty Synthesis Supported Synthesis Supported Reagents Synthetic Reagents Oxidizing Reagents