ChemicalBook >> CAS DataBase List >>ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
- CAS No.
- 1235-21-8
- Chemical Name:
- ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
- Synonyms
- AURORA KA-1148;acetonyltriphenyl-phosphoniuchloride;OxopropyltriphenylphosphoniuM chlorid;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE;Acetonyltriphenylphosphonium chloride,99%;Acetonyltriphenylphosphonium Chloride >2-oxopropyl(triphenyl)phosphanium chloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%;(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE;2-Oxopropyltriphenylphosphonium chloride 98%
- CBNumber:
- CB5414572
- Molecular Formula:
- C21H20ClOP
- Molecular Weight:
- 354.81
- MDL Number:
- MFCD00011813
- MOL File:
- 1235-21-8.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 243-245 °C(lit.) |
|---|---|
| storage temp. | Store below +30°C. |
| form | solid |
| color | White to Light yellow to Light orange |
| Water Solubility | Soluble in hot water. |
| Sensitive | Hygroscopic |
| CAS DataBase Reference | 1235-21-8(CAS DataBase Reference) |
| FDA UNII | 5WP8HJ7H8U |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 22-24/25-S24/25-S22-60-37-26 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TA1841000 | |||||||||
| F | 3 | |||||||||
| HS Code | 29319019 | |||||||||
| Toxicity | mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01535, | |||||||||
| NFPA 704 |
|
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.41028 | Acetonyltriphenylphosphonium chloride for synthesis | 1235-21-8 | 25g | $110 | 2023-01-07 | Buy |
| TCI Chemical | A1305 | Acetonyltriphenylphosphonium Chloride >98.0%(HPLC)(T) | 1235-21-8 | 25g | $37 | 2024-03-01 | Buy |
| Alfa Aesar | A14691 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 25g | $38.65 | 2024-03-01 | Buy |
| Alfa Aesar | A14691 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 100g | $129.65 | 2024-03-01 | Buy |
| Alfa Aesar | A14691 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 500g | $485.65 | 2024-03-01 | Buy |
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
WHITE TO SLIGHTLY BEIGE FINE CRYSTALLINE POWDER
Uses
Used to investigate the antimycobacterial activities of Me alkenyl quinolones
Reactant for synthesis of:
- Unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination
- Fused oxygen and nitrogen heterocycles via regioselective cyclocondensation
Reactant for Wittig olefinations
Uses
Acetonyltriphenylphosphonium chloride is used to investigate the antimycobacterial activities of Me alkenyl quinolones. It is used as a reactant for synthesis of unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination.
Purification Methods
Recrystallise it from CHCl3/*C6H6/pet ether (b 60-80o) or by dissolving it in CHCl3 and pouring it into dry Et2O. max nm() 255(3,600), 262(3,700), 268(4,000) and 275(3,100). The iodide salt crystallises from H2O and has m 207-209o. [Ramirez & Dershowitz J Org Chem 22 41 1957.] Itisan IRRITANT and is hygroscopic. When shaken with a 10% aqueous solution of Na2CO3 (8hours) it gives acetylmethylene triphenyl phosphorane which is recrystallised from MeOH/H2O and after drying at 70o/0.1mm has m 205-206o. UV: nm() 268 (6600), 275 (6500) and 288 (5700), IR: max 1529 (s), 1470 (m), 1425 (s), max 1374 (m), 1105 and 978 (s) (cm-1). [Ramirez & Dershowitz J Org Chem 22 41, 44 1957, Beilstein 16 H 761, 16 II 373.]
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 178)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15957 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 15093356674; | laboratory@coreychem.com | China | 30255 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Changzhou Xuanming Pharmaceutical Technology Co., Ltd. | +8618068519287 | sales@xuanmingchem.com | China | 823 | 58 |
| Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
| Aston Chemical | 13000000000 | sales@astonchem.com | United States | 1634 | 58 |
| Wuhan Fortuna Chemical Co., Ltd | +86-27-59207850 +86-13986145403 | info@fortunachem.com | China | 5999 | 58 |
| Baoji Guokang Bio-Technology Co., Ltd. | 0917-3909592 13892490616 | gksales1@gk-bio.com | China | 9335 | 58 |
View Lastest Price from ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-02-24 | Acetonyltriphenylphosphonium chloride
1235-21-8
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2022-10-11 | ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
1235-21-8
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2021-07-13 | Acetonyltriphenylphosphonium chloride
1235-21-8
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- Acetonyltriphenylphosphonium chloride
1235-21-8
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
1235-21-8
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Acetonyltriphenylphosphonium chloride
1235-21-8
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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Acetonyltriphenylphosphonium chloride for synthesis
2-oxopropyl(triphenyl)phosphanium chloride
acetonyltriphenyl-phosphoniuchloride
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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
AURORA KA-1148
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%
Acetonyltriphenylphosphonium chloride,99%
(Acetylmethylene)triphenylphosphoniumchloride
Acetonyltriphenylphosphonium Chloride >
Phosphonium, (2-oxopropyl)triphenyl-, chloride (1:1)
1235-21-8
CH3COCH2PClC6H53
C21H20ClOP
C21H20OPCl
C21H20OP
C21H20CIOP
C-C Bond Formation
Olefination
Synthetic Reagents
Wittig Reagents
Phosphonium Compounds
Wittig Reaction
Wittig & Horner-Emmons Reaction
Phosphonium Compounds
Synthetic Organic Chemistry
Wittig & Horner-Emmons Reaction
Wittig Reaction