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3-ETHOXY-3-OXOPROPYLZINC BROMIDE

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Structure
3-ETHOXY-3-OXOPROPYLZINC BROMIDE structure
CAS No.
193065-68-8
Chemical Name:
3-ETHOXY-3-OXOPROPYLZINC BROMIDE
Synonyms
(3-ethoxy-3-oxopropyl)zinc(II) broMide;zinc bromide soL;3-Ethoxy-3-oxopropyL;3-ETHOXY-3-OXOPROPYLZINC BROMIDE;2-(Ethoxycarbonyl)ethylzinc bromide;3-ethoxy-3-oxopropylzinc bromide solution;2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF;3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF;3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF;3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN
CBNumber:
CB5767797
Molecular Formula:
C5H9BrO2Zn
Molecular Weight:
246.41
MDL Number:
MFCD00671976
MOL File:
193065-68-8.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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3-ETHOXY-3-OXOPROPYLZINC BROMIDE Properties

Density 0.972 g/mL at 25 °C
Flash point 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H261-H318-H333-H225-H302-H314-H335-H351
Precautionary statements  P210-P260-P280-P305+P351+P338-P370+P378-P403+P235-P223-P303+P361+P353-P405-P501a
Hazard Codes  F,Xi,Xn
Risk Statements  11-19-36/37-40
Safety Statements  16-26-29-33-36/37
RIDADR  UN 3399 4.3/PG 2
WGK Germany  1
HazardClass  4.3
PackingGroup  II
HS Code  29319090
NFPA 704
3
3 2
W

3-ETHOXY-3-OXOPROPYLZINC BROMIDE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 498521 3-Ethoxy-3-oxopropylzinc bromide solution 0.5 M in THF 193065-68-8 50ml $221.6 2024-03-01 Buy
Alfa Aesar H26739 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF 193065-68-8 50ml $190 2024-03-01 Buy
Rieke Metals 2010 3-Ethoxy-3-oxopropylzincbromide 193065-68-8 100mL $460 2021-12-16 Buy
American Custom Chemicals Corporation ING0005827 3-ETHOXY-3-OXOPROPYLZINC BROMIDE 95.00% 193065-68-8 100ML $2795.1 2021-12-16 Buy
American Custom Chemicals Corporation ING0005827 3-ETHOXY-3-OXOPROPYLZINC BROMIDE 95.00% 193065-68-8 500ML $5313 2021-12-16 Buy
Product number Packaging Price Buy
498521 50ml $221.6 Buy
H26739 50ml $190 Buy
2010 100mL $460 Buy
ING0005827 100ML $2795.1 Buy
ING0005827 500ML $5313 Buy

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Chemical Properties,Uses,Production

Uses

3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in:

  • Synthesis of γ-keto esters from aryl chlorides.
  • Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides.
  • Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Suppliers

Global( 27)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30132 84
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Hanhong Scientific Co.,Ltd. China 42982 64
Syntechem Co.,Ltd info@syntechem.com China 12990 57
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Infinity SCI 400-400-1062016 17800804092 admin@infsci.com China 698 55
Panjin Infinity Scientific CO. LTD 400-1062016 18612996721 hao@infsci.com China 328 58
Aikon International Limited 025-66113011 13155353615 qzhang@aikonchem.com China 15396 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. +86-400-002-6226 13028896684 sales@rrkchem.com China 55896 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
Energy Chemical 61
Shanghai Hanhong Scientific Co.,Ltd. 64
Syntechem Co.,Ltd 57
Sigma-Aldrich 80
Infinity SCI 55
Panjin Infinity Scientific CO. LTD 58
Aikon International Limited 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. 58

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3-ETHOXY-3-OXOPROPYLZINC BROMIDE 3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN 3-ethoxy-3-oxopropylzinc bromide solution 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF 2-(Ethoxycarbonyl)ethylzinc bromide 3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF 3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF 3-Ethoxy-3-oxopropyL zinc bromide soL (3-ethoxy-3-oxopropyl)zinc(II) broMide 193065-68-8 BrZnCH2CH2COOCH2CH3 C5H9BrO2Zn C2H5O2CCH2CH2ZnBr Reike and Organozinc Reagents Organometallic Reagents Organozinc Halides Alkyl Alkyl Organozinc Halides Reike and Organozinc Reagents