ChemicalBook >> CAS DataBase List >>(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE structure

CAS No.: 136705-62-9

Chemical Name:: (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

Synonyms: (R,R)-ET-BPE;Bisdiethylphospholanoethane;(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE;(+)-1,2-bis-((2R,5R)-2,5-Diethylphospholano)ethane;(+)-1,2-Bis[(2R,5R)-2,5-diethyl-1-phospholanyl]ethane, 97+%;(+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane (R,R)-Et-BPE;(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane, Kanata purity;(+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane,98+%(R,R)-Et-BPE;Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-diethyl-, (2R,2'R,5R,5'R)-;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]ethyl]-2,5-diethylphospholane

CBNumber:: CB6165079

Molecular Formula:: C18H36P2

Molecular Weight:: 314.43

MDL Number:: MFCD01073768

MOL File:: 136705-62-9.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

Request For Quotation

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE Properties

alpha	+320° ±4° (c 1, hexane)
Boiling point	104-106°C 0,5mm
Density	0.939 g/mL at 25 °C
refractive index	n20/D 1.5249
Flash point	110 °C
form	liquid
color	colorless to pale-yellow
Sensitive	Air Sensitive
FDA UNII	0339L99K79

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS07
Signal word	Warning
Hazard statements	H250-H252-H315-H319-H335
Precautionary statements	P210-P222-P305+P351+P338-P405-P422a-P501a
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
HazardClass	4.2

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE price More Price(8)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	668478	(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane kanata purity	136705-62-9	100mg	$37.68	2024-03-01	Buy
Sigma-Aldrich	668478	(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane kanata purity	136705-62-9	500mg	$287	2024-03-01	Buy
Alfa Aesar	H60447	(+)-1,2-Bis[(2R,5R)-2,5-diethyl-1-phospholanyl]ethane, 97+%	136705-62-9	1g	$404	2021-12-16	Buy
Alfa Aesar	H60447	(+)-1,2-Bis[(2R,5R)-2,5-diethyl-1-phospholanyl]ethane, 97+%	136705-62-9	250mg	$130	2021-12-16	Buy
Strem Chemicals	15-0101	(+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane, 98+% (R,R)-Et-BPE	136705-62-9	100mg	$79	2024-03-01	Buy

Product number	Packaging	Price	Buy
668478	100mg	$37.68	Buy
668478	500mg	$287	Buy
H60447	1g	$404	Buy
H60447	250mg	$130	Buy
15-0101	100mg	$79	Buy

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE Chemical Properties,Uses,Production

Reaction

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Forms superior catalysts for asymmetric reductive aminations.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Palladium catalyzed asymmetric phosphination.

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE Suppliers

Global( 30)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52861	58
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	peter68@ptchemgroup.com	China	35453	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	50000	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	52927	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40240	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30132	84
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44700	61
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80
Shanghai Anyinuo Biomedical Technology Co., Ltd.	021-34625901	420970979@qq.com	China	5751	58

Supplier	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
Energy Chemical	61
Sigma-Aldrich	80
Shanghai Anyinuo Biomedical Technology Co., Ltd.	58

136705-62-9((+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE)Related Search:

Metformin hydrochloride (-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE 1,2-BIS(DIETHYLPHOSPHINO)ETHANE 1,2-BIS((2S,5S)-2,5-DIISOPROPYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

1of2

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE (R,R)-ET-BPE Bisdiethylphospholanoethane (+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane, Kanata purity (+)-1,2-Bis[(2R,5R)-2,5-diethyl-1-phospholanyl]ethane, 97+% (+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane,98+%(R,R)-Et-BPE (+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane (R,R)-Et-BPE (2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]ethyl]-2,5-diethylphospholane Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-diethyl-, (2R,2'R,5R,5'R)- (+)-1,2-bis-((2R,5R)-2,5-Diethylphospholano)ethane 136705-62-9 C8H16PCH2CH2PC8H16 C18H36P2 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Privileged Ligands DuPhos/BPE organophosphine ligand